Purification of Aqueous Media by Biochars: Feedstock Type Effect on Silver Nanoparticles Removal

Due to the harmful effects of nanoparticles in the environment, their effective removal from aqueous media is of great importance. This paper described the research on the silver nanoparticles (Ag-NPs) sorption on biochars obtained from different feedstock types. The sorbents were produced through p...

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Bibliographic Details
Main Authors: Agnieszka Tomczyk, Katarzyna Szewczuk-Karpisz, Zofia Sokołowska, Milena Kercheva, Emil Dimitrov
Format: Article
Language:English
Published: MDPI AG 2020-06-01
Series:Molecules
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Online Access:https://www.mdpi.com/1420-3049/25/12/2930
Description
Summary:Due to the harmful effects of nanoparticles in the environment, their effective removal from aqueous media is of great importance. This paper described the research on the silver nanoparticles (Ag-NPs) sorption on biochars obtained from different feedstock types. The sorbents were produced through pyrolysis (double-barrel method) of the vineyard (BV), paulownia tree<span> (BP), and</span> tobacco (BT). BV exhibited the highest specific surface area, porosity, value of variable surface charge, and content of surface acidic functional groups among the used biochars. The pseudo-second order model best described the obtained adsorption kinetics, whereas the Freundlich model accounted for the registered adsorption data<span>. The Ag-NPs removal was highly efficient in the case of BV, especially in the nanoparticle concentration range 50–500 mg/L.</span> Thus, this biochar can be considered as an ecofriendly, effective, low-cost organic adsorbent, potentially used in the aqueous media purification.
ISSN:1420-3049