Conditions for the formation of a non-autonomous phase at the structural deformation of complex vanadium oxides

A new previously unknown effect of a reversible transition from a single-phase system to a heterophase system containing a non-autonomous phase was observed during thermal and chemical deformations of the Zn2-2xCd2xV2O7 structure.The role of local symmetry in the formation of the non-autonomous phas...

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Main Authors:	M. V. Rotermel, T. I. Krasnenko, S. A. Petrova, S. G. Titova
Format:	Article
Language:	English
Published:	Uralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina 2018-05-01
Series:	Chimica Techno Acta
Subjects:	non-autonomous phase volume thermal expansion M2V2O7
Online Access:	https://journals.urfu.ru/index.php/chimtech/article/view/3120

id	doaj-76881bd3c8ac4366a5645c607c5a19e5
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spelling	doaj-76881bd3c8ac4366a5645c607c5a19e52020-11-25T00:40:32ZengUralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina Chimica Techno Acta2409-56132411-14142018-05-0151869110.15826/chimtech.2018.5.1.062653Conditions for the formation of a non-autonomous phase at the structural deformation of complex vanadium oxidesM. V. Rotermel0T. I. Krasnenko1S. A. Petrova2S. G. Titova3Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, EkaterinburgInstitute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, EkaterinburgInstitute of Metallurgy, Ural Branch of the Russian Academy of Sciences, EkaterinburgInstitute of Metallurgy, Ural Branch of the Russian Academy of Sciences, EkaterinburgA new previously unknown effect of a reversible transition from a single-phase system to a heterophase system containing a non-autonomous phase was observed during thermal and chemical deformations of the Zn2-2xCd2xV2O7 structure.The role of local symmetry in the formation of the non-autonomous phase is shown on the basis of X-ray diffraction studies in situ and a comparative crystal-chemical analysis of the structural deformations of isoform monoclinic solid solutions of zinc and copper pyrovanadates with zero volumetric thermal expansion.https://journals.urfu.ru/index.php/chimtech/article/view/3120non-autonomous phasevolume thermal expansionM2V2O7
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	M. V. Rotermel T. I. Krasnenko S. A. Petrova S. G. Titova
spellingShingle	M. V. Rotermel T. I. Krasnenko S. A. Petrova S. G. Titova Conditions for the formation of a non-autonomous phase at the structural deformation of complex vanadium oxides Chimica Techno Acta non-autonomous phase volume thermal expansion M2V2O7
author_facet	M. V. Rotermel T. I. Krasnenko S. A. Petrova S. G. Titova
author_sort	M. V. Rotermel
title	Conditions for the formation of a non-autonomous phase at the structural deformation of complex vanadium oxides
title_short	Conditions for the formation of a non-autonomous phase at the structural deformation of complex vanadium oxides
title_full	Conditions for the formation of a non-autonomous phase at the structural deformation of complex vanadium oxides
title_fullStr	Conditions for the formation of a non-autonomous phase at the structural deformation of complex vanadium oxides
title_full_unstemmed	Conditions for the formation of a non-autonomous phase at the structural deformation of complex vanadium oxides
title_sort	conditions for the formation of a non-autonomous phase at the structural deformation of complex vanadium oxides
publisher	Uralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina
series	Chimica Techno Acta
issn	2409-5613 2411-1414
publishDate	2018-05-01
description	A new previously unknown effect of a reversible transition from a single-phase system to a heterophase system containing a non-autonomous phase was observed during thermal and chemical deformations of the Zn2-2xCd2xV2O7 structure.The role of local symmetry in the formation of the non-autonomous phase is shown on the basis of X-ray diffraction studies in situ and a comparative crystal-chemical analysis of the structural deformations of isoform monoclinic solid solutions of zinc and copper pyrovanadates with zero volumetric thermal expansion.
topic	non-autonomous phase volume thermal expansion M2V2O7
url	https://journals.urfu.ru/index.php/chimtech/article/view/3120
work_keys_str_mv	AT mvrotermel conditionsfortheformationofanonautonomousphaseatthestructuraldeformationofcomplexvanadiumoxides AT tikrasnenko conditionsfortheformationofanonautonomousphaseatthestructuraldeformationofcomplexvanadiumoxides AT sapetrova conditionsfortheformationofanonautonomousphaseatthestructuraldeformationofcomplexvanadiumoxides AT sgtitova conditionsfortheformationofanonautonomousphaseatthestructuraldeformationofcomplexvanadiumoxides
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Conditions for the formation of a non-autonomous phase at the structural deformation of complex vanadium oxides

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