POM@MOF Hybrids: Synthesis and Applications

The hybrid materials that are created by supporting or incorporating polyoxometalates (POMs) into/onto metal–organic frameworks (MOFs) have a unique set of properties. They combine the strong acidity, oxygen-rich surface, and redox capability of POMs, while overcoming their drawbacks, such as diffic...

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Main Authors:	Jiamin Sun, Sara Abednatanzi, Pascal Van Der Voort, Ying-Ya Liu, Karen Leus
Format:	Article
Language:	English
Published:	MDPI AG 2020-05-01
Series:	Catalysts
Subjects:	metal–organic frameworks polyoxometalates hybrid materials synthesis catalysis
Online Access:	https://www.mdpi.com/2073-4344/10/5/578

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spelling	doaj-766a03e21e5f48e28d7ad10fe6eae97a2020-11-25T04:03:13ZengMDPI AGCatalysts2073-43442020-05-011057857810.3390/catal10050578POM@MOF Hybrids: Synthesis and ApplicationsJiamin Sun0Sara Abednatanzi1Pascal Van Der Voort2Ying-Ya Liu3Karen Leus4COMOC—Center for Ordered Materials, Organometallics and Catalysis, Department of Chemistry, Ghent University, Krijgslaan 281, building S3, 9000 Ghent, BelgiumCOMOC—Center for Ordered Materials, Organometallics and Catalysis, Department of Chemistry, Ghent University, Krijgslaan 281, building S3, 9000 Ghent, BelgiumCOMOC—Center for Ordered Materials, Organometallics and Catalysis, Department of Chemistry, Ghent University, Krijgslaan 281, building S3, 9000 Ghent, BelgiumState Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, ChinaCOMOC—Center for Ordered Materials, Organometallics and Catalysis, Department of Chemistry, Ghent University, Krijgslaan 281, building S3, 9000 Ghent, BelgiumThe hybrid materials that are created by supporting or incorporating polyoxometalates (POMs) into/onto metal–organic frameworks (MOFs) have a unique set of properties. They combine the strong acidity, oxygen-rich surface, and redox capability of POMs, while overcoming their drawbacks, such as difficult handling, a low surface area, and a high solubility. MOFs are ideal hosts because of their high surface area, long-range ordered structure, and high tunability in terms of the pore size and channels. In some cases, MOFs add an extra dimension to the functionality of hybrids. This review summarizes the recent developments in the field of POM@MOF hybrids. The most common applied synthesis strategies are discussed, together with major applications, such as their use in catalysis (organocatalysis, electrocatalysis, and photocatalysis). The more than 100 papers on this topic have been systematically summarized in a handy table, which covers almost all of the work conducted in this field up to now.https://www.mdpi.com/2073-4344/10/5/578metal–organic frameworkspolyoxometalateshybrid materialssynthesiscatalysis
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Jiamin Sun Sara Abednatanzi Pascal Van Der Voort Ying-Ya Liu Karen Leus
spellingShingle	Jiamin Sun Sara Abednatanzi Pascal Van Der Voort Ying-Ya Liu Karen Leus POM@MOF Hybrids: Synthesis and Applications Catalysts metal–organic frameworks polyoxometalates hybrid materials synthesis catalysis
author_facet	Jiamin Sun Sara Abednatanzi Pascal Van Der Voort Ying-Ya Liu Karen Leus
author_sort	Jiamin Sun
title	POM@MOF Hybrids: Synthesis and Applications
title_short	POM@MOF Hybrids: Synthesis and Applications
title_full	POM@MOF Hybrids: Synthesis and Applications
title_fullStr	POM@MOF Hybrids: Synthesis and Applications
title_full_unstemmed	POM@MOF Hybrids: Synthesis and Applications
title_sort	pom@mof hybrids: synthesis and applications
publisher	MDPI AG
series	Catalysts
issn	2073-4344
publishDate	2020-05-01
description	The hybrid materials that are created by supporting or incorporating polyoxometalates (POMs) into/onto metal–organic frameworks (MOFs) have a unique set of properties. They combine the strong acidity, oxygen-rich surface, and redox capability of POMs, while overcoming their drawbacks, such as difficult handling, a low surface area, and a high solubility. MOFs are ideal hosts because of their high surface area, long-range ordered structure, and high tunability in terms of the pore size and channels. In some cases, MOFs add an extra dimension to the functionality of hybrids. This review summarizes the recent developments in the field of POM@MOF hybrids. The most common applied synthesis strategies are discussed, together with major applications, such as their use in catalysis (organocatalysis, electrocatalysis, and photocatalysis). The more than 100 papers on this topic have been systematically summarized in a handy table, which covers almost all of the work conducted in this field up to now.
topic	metal–organic frameworks polyoxometalates hybrid materials synthesis catalysis
url	https://www.mdpi.com/2073-4344/10/5/578
work_keys_str_mv	AT jiaminsun pommofhybridssynthesisandapplications AT saraabednatanzi pommofhybridssynthesisandapplications AT pascalvandervoort pommofhybridssynthesisandapplications AT yingyaliu pommofhybridssynthesisandapplications AT karenleus pommofhybridssynthesisandapplications
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POM@MOF Hybrids: Synthesis and Applications

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