(Benzonitrile-κN)chlorido[hydridotris(pyrazol-1-yl-κN2)borato](triphenylphosphine-κP)ruthenium(II) ethanol solvate

The reaction of [Ru(C9H10BN6)Cl(C18H15P)2] with benzonitrile leads to crystals of the title compound, [Ru(C9H10BN6)Cl(C18H15P)(C7H5N)]·C2H5OH. In the crystal structure, the environment about the ruthenium metal center corresponds to a slightly distorted octahedron with an average N&...

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Main Authors: Hung-Chun Tong, Yu-Chen Hung, Po-Yo Wang, Chia-Her Lin, Yih-Hsing Lo
Format: Article
Language:English
Published: International Union of Crystallography 2009-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809010265
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spelling doaj-7648a9cd21f445058e5c01d28d3259292020-11-25T01:58:58ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-04-01654m438m43810.1107/S1600536809010265(Benzonitrile-κN)chlorido[hydridotris(pyrazol-1-yl-κN2)borato](triphenylphosphine-κP)ruthenium(II) ethanol solvateHung-Chun TongYu-Chen HungPo-Yo WangChia-Her LinYih-Hsing LoThe reaction of [Ru(C9H10BN6)Cl(C18H15P)2] with benzonitrile leads to crystals of the title compound, [Ru(C9H10BN6)Cl(C18H15P)(C7H5N)]·C2H5OH. In the crystal structure, the environment about the ruthenium metal center corresponds to a slightly distorted octahedron with an average N—Ru—N bite angle of the Tp ligand of 86.6 (2)°. http://scripts.iucr.org/cgi-bin/paper?S1600536809010265
collection DOAJ
language English
format Article
sources DOAJ
author Hung-Chun Tong
Yu-Chen Hung
Po-Yo Wang
Chia-Her Lin
Yih-Hsing Lo
spellingShingle Hung-Chun Tong
Yu-Chen Hung
Po-Yo Wang
Chia-Her Lin
Yih-Hsing Lo
(Benzonitrile-κN)chlorido[hydridotris(pyrazol-1-yl-κN2)borato](triphenylphosphine-κP)ruthenium(II) ethanol solvate
Acta Crystallographica Section E
author_facet Hung-Chun Tong
Yu-Chen Hung
Po-Yo Wang
Chia-Her Lin
Yih-Hsing Lo
author_sort Hung-Chun Tong
title (Benzonitrile-κN)chlorido[hydridotris(pyrazol-1-yl-κN2)borato](triphenylphosphine-κP)ruthenium(II) ethanol solvate
title_short (Benzonitrile-κN)chlorido[hydridotris(pyrazol-1-yl-κN2)borato](triphenylphosphine-κP)ruthenium(II) ethanol solvate
title_full (Benzonitrile-κN)chlorido[hydridotris(pyrazol-1-yl-κN2)borato](triphenylphosphine-κP)ruthenium(II) ethanol solvate
title_fullStr (Benzonitrile-κN)chlorido[hydridotris(pyrazol-1-yl-κN2)borato](triphenylphosphine-κP)ruthenium(II) ethanol solvate
title_full_unstemmed (Benzonitrile-κN)chlorido[hydridotris(pyrazol-1-yl-κN2)borato](triphenylphosphine-κP)ruthenium(II) ethanol solvate
title_sort (benzonitrile-κn)chlorido[hydridotris(pyrazol-1-yl-κn2)borato](triphenylphosphine-κp)ruthenium(ii) ethanol solvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-04-01
description The reaction of [Ru(C9H10BN6)Cl(C18H15P)2] with benzonitrile leads to crystals of the title compound, [Ru(C9H10BN6)Cl(C18H15P)(C7H5N)]·C2H5OH. In the crystal structure, the environment about the ruthenium metal center corresponds to a slightly distorted octahedron with an average N—Ru—N bite angle of the Tp ligand of 86.6 (2)°.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809010265
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AT yuchenhung benzonitrileamp954nchloridohydridotrispyrazol1ylamp954n2boratotriphenylphosphineamp954prutheniumiiethanolsolvate
AT poyowang benzonitrileamp954nchloridohydridotrispyrazol1ylamp954n2boratotriphenylphosphineamp954prutheniumiiethanolsolvate
AT chiaherlin benzonitrileamp954nchloridohydridotrispyrazol1ylamp954n2boratotriphenylphosphineamp954prutheniumiiethanolsolvate
AT yihhsinglo benzonitrileamp954nchloridohydridotrispyrazol1ylamp954n2boratotriphenylphosphineamp954prutheniumiiethanolsolvate
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