Synthesis and crystal structure of tricarbonylchlorido{1-[(pyridin-2-ylmethylidene)amino]adamantane}rhenium(I)

Synthesis and crystal structure of tricarbonylchlorido{1-[(pyridin-2-ylmethylidene)amino]adamantane}rhenium(I)

The title compound, [ReCl(pyAm)(CO)3], where pyAm is 1-[(pyridin-2-ylmethylidene)amino]adamantane (C16H20N2), was synthesized from the reaction of [ReCl(CO)5] and pyAm in an equimolar ratio. The ReI atom resides in an octahedral C3ClN2 coordination sphere. The Re—C bond trans to the chloride ligand...

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Bibliographic Details
Main Authors: Jorge Jimenez, Indranil Chakraborty, Pradip Mascharak
Format: Article
Language:English
Published: International Union of Crystallography 2016-09-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
rhenium complex
fac-Re(CO)3
lipophilicity
adamantane motif
Online Access:http://scripts.iucr.org/cgi-bin/paper?S205698901601255X

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http://scripts.iucr.org/cgi-bin/paper?S205698901601255X

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