Aqua(trifluoromethanesulfonato)bis(1,3,7-trimethylpurine-2,6-dione)silver(I)

Aqua(trifluoromethanesulfonato)bis(1,3,7-trimethylpurine-2,6-dione)silver(I)

In the title compound, [Ag(CF3SO3)(C8H10N4O2)2(H2O)], the AgI atom is coordinated by two caffeine N atoms and, at longer distances, two O atoms of a coordinated water molecule and the trifluoromethanesulfonate anion, resulting in an AgN2O2 seesaw geometry. The caffeine molecules are roughly coplanar...

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Main Authors: Edward R. T. Tiekink, Tyler Miller, Hadi D. Arman
Format: Article
Language:English
Published: International Union of Crystallography 2010-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810035300
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spelling doaj-762c92af913a499e9df18ceb935dc9152020-11-24T22:08:23ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-10-016610m1211m121110.1107/S1600536810035300Aqua(trifluoromethanesulfonato)bis(1,3,7-trimethylpurine-2,6-dione)silver(I)Edward R. T. TiekinkTyler MillerHadi D. ArmanIn the title compound, [Ag(CF3SO3)(C8H10N4O2)2(H2O)], the AgI atom is coordinated by two caffeine N atoms and, at longer distances, two O atoms of a coordinated water molecule and the trifluoromethanesulfonate anion, resulting in an AgN2O2 seesaw geometry. The caffeine molecules are roughly coplanar [dihedral angle = 5.81 (5)°]. In the crystal, molecules self-assemble into a linear supramolecular chain along the c axis via O—H...O hydrogen bonds involving the coordinated water moledcule and carbonyl O atoms. The packing is consolidated by weak C—H...O interactions. http://scripts.iucr.org/cgi-bin/paper?S1600536810035300
collection DOAJ
language English
format Article
sources DOAJ
author Edward R. T. Tiekink
Tyler Miller
Hadi D. Arman
spellingShingle Edward R. T. Tiekink
Tyler Miller
Hadi D. Arman
Aqua(trifluoromethanesulfonato)bis(1,3,7-trimethylpurine-2,6-dione)silver(I)
Acta Crystallographica Section E
author_facet Edward R. T. Tiekink
Tyler Miller
Hadi D. Arman
author_sort Edward R. T. Tiekink
title Aqua(trifluoromethanesulfonato)bis(1,3,7-trimethylpurine-2,6-dione)silver(I)
title_short Aqua(trifluoromethanesulfonato)bis(1,3,7-trimethylpurine-2,6-dione)silver(I)
title_full Aqua(trifluoromethanesulfonato)bis(1,3,7-trimethylpurine-2,6-dione)silver(I)
title_fullStr Aqua(trifluoromethanesulfonato)bis(1,3,7-trimethylpurine-2,6-dione)silver(I)
title_full_unstemmed Aqua(trifluoromethanesulfonato)bis(1,3,7-trimethylpurine-2,6-dione)silver(I)
title_sort aqua(trifluoromethanesulfonato)bis(1,3,7-trimethylpurine-2,6-dione)silver(i)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-10-01
description In the title compound, [Ag(CF3SO3)(C8H10N4O2)2(H2O)], the AgI atom is coordinated by two caffeine N atoms and, at longer distances, two O atoms of a coordinated water molecule and the trifluoromethanesulfonate anion, resulting in an AgN2O2 seesaw geometry. The caffeine molecules are roughly coplanar [dihedral angle = 5.81 (5)°]. In the crystal, molecules self-assemble into a linear supramolecular chain along the c axis via O—H...O hydrogen bonds involving the coordinated water moledcule and carbonyl O atoms. The packing is consolidated by weak C—H...O interactions.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810035300
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AT tylermiller aquatrifluoromethanesulfonatobis137trimethylpurine26dionesilveri
AT hadidarman aquatrifluoromethanesulfonatobis137trimethylpurine26dionesilveri
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