(S)-1,5-Dibenzyl-3-tert-butylimidazolidin-4-one

(S)-1,5-Dibenzyl-3-tert-butylimidazolidin-4-one

The title compound, C21H26N2O, was obtained as an unexpected by-product when attempting to prepare (S)-2-benzyl-N-tert-butyl-1,2,3,4-tetrahydroisoquinoline-3-carboxamide from (S)-2-benzylamino-N-tert-butyl-3-phenylpropanamide and dimethoxymethane. The molecules are linked by weak C—H...O h...

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Main Authors: Jian-Feng Zheng, Jian-Nan Guo, Su-Yu Huang, Bo Teng, Li-Ren Jin
Format: Article
Language:English
Published: International Union of Crystallography 2008-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808018461
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spelling doaj-761606f81d5441c18562a6c835977b4f2020-11-24T23:56:38ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-07-01647o1330o133010.1107/S1600536808018461(S)-1,5-Dibenzyl-3-tert-butylimidazolidin-4-oneJian-Feng ZhengJian-Nan GuoSu-Yu HuangBo TengLi-Ren JinThe title compound, C21H26N2O, was obtained as an unexpected by-product when attempting to prepare (S)-2-benzyl-N-tert-butyl-1,2,3,4-tetrahydroisoquinoline-3-carboxamide from (S)-2-benzylamino-N-tert-butyl-3-phenylpropanamide and dimethoxymethane. The molecules are linked by weak C—H...O hydrogen bonds, generating linear chains parallel to the b axis. C—H...π interactions provide further stability for the crystal structure. The planes of the two phenyl rings make a dihedral angle of 84.1 (1)°. The absolute configuration was known from the starting material.http://scripts.iucr.org/cgi-bin/paper?S1600536808018461
collection DOAJ
language English
format Article
sources DOAJ
author Jian-Feng Zheng
Jian-Nan Guo
Su-Yu Huang
Bo Teng
Li-Ren Jin
spellingShingle Jian-Feng Zheng
Jian-Nan Guo
Su-Yu Huang
Bo Teng
Li-Ren Jin
(S)-1,5-Dibenzyl-3-tert-butylimidazolidin-4-one
Acta Crystallographica Section E
author_facet Jian-Feng Zheng
Jian-Nan Guo
Su-Yu Huang
Bo Teng
Li-Ren Jin
author_sort Jian-Feng Zheng
title (S)-1,5-Dibenzyl-3-tert-butylimidazolidin-4-one
title_short (S)-1,5-Dibenzyl-3-tert-butylimidazolidin-4-one
title_full (S)-1,5-Dibenzyl-3-tert-butylimidazolidin-4-one
title_fullStr (S)-1,5-Dibenzyl-3-tert-butylimidazolidin-4-one
title_full_unstemmed (S)-1,5-Dibenzyl-3-tert-butylimidazolidin-4-one
title_sort (s)-1,5-dibenzyl-3-tert-butylimidazolidin-4-one
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-07-01
description The title compound, C21H26N2O, was obtained as an unexpected by-product when attempting to prepare (S)-2-benzyl-N-tert-butyl-1,2,3,4-tetrahydroisoquinoline-3-carboxamide from (S)-2-benzylamino-N-tert-butyl-3-phenylpropanamide and dimethoxymethane. The molecules are linked by weak C—H...O hydrogen bonds, generating linear chains parallel to the b axis. C—H...π interactions provide further stability for the crystal structure. The planes of the two phenyl rings make a dihedral angle of 84.1 (1)°. The absolute configuration was known from the starting material.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808018461
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