Photoinduced Oxygen Evolution Catalysis Promoted by Polyoxometalate Salts of Cationic Photosensitizers

Photoinduced Oxygen Evolution Catalysis Promoted by Polyoxometalate Salts of Cationic Photosensitizers

The insoluble salt Cs15K[Co9(H2O)6(OH)3(HPO4)2(PW9O34)3] (CsCo9) is tested as heterogeneous oxygen evolution catalyst in light-induced experiments, when combined with the homogeneous photosensitizer [Ru(bpy)3]2+ and the oxidant Na2S2O8 in neutral pH. Oxygen evolution occurs in parallel to a solid tr...

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Bibliographic Details
Main Authors: Joaquín Soriano-López, Fangyuan Song, Greta R. Patzke, J. R. Galan-Mascaros
Format: Article
Language:English
Published: Frontiers Media S.A. 2018-08-01
Series:Frontiers in Chemistry
Subjects:
water splitting
oxygen evolution
polyoxometalates
photosensitizer
cobalt
Online Access:https://www.frontiersin.org/article/10.3389/fchem.2018.00302/full

Internet

https://www.frontiersin.org/article/10.3389/fchem.2018.00302/full

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