Crystal structure of (2,2′-bipyridine-κ2N,N′)-trans-bis(tert-butyldimethylsilyloxy)-cis-dioxidomolybdenum(VI)

Crystal structure of (2,2′-bipyridine-κ2N,N′)-trans-bis(tert-butyldimethylsilyloxy)-cis-dioxidomolybdenum(VI)

In the title compound, [(tBuSiMe2O)2MoO2(2,2′-bipyridine)] or [Mo(C6H15OSi)2O2(C10H8N2)], the MoVI atom has a distorted octahedral environment with the siloxy substituents occupying the trans positions. The complex contains a rare (R3SiO)2MO2 (M = Mo, W) structural motif and was formed in a reaction...

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Bibliographic Details
Main Authors: Mikhail E. Minyaev, Alexander A. Vinogradov, Ilya E. Nifant'ev, Andrei V. Churakov
Format: Article
Language:English
Published: International Union of Crystallography 2018-07-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
molybdenum(VI)
rare structural motif
coordination compounds
NMR
hydrogen bonding.
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989018008472

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http://scripts.iucr.org/cgi-bin/paper?S2056989018008472

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