(Z)-Ethyl 3-[bis(4-chloro-3-ethyl-1-methyl-1H-pyrazol-5-ylcarbonyl)amino]-3-(4-chlorophenyl)-2-cyanopropanoate

(Z)-Ethyl 3-[bis(4-chloro-3-ethyl-1-methyl-1H-pyrazol-5-ylcarbonyl)amino]-3-(4-chlorophenyl)-2-cyanopropanoate

The title compound, C26H25Cl3N6O4, was prepared by the reaction of (Z)-ethyl 3-amino-3-(4-chlorophenyl)-2-cyanoacrylate and 4-chloro-3-ethyl-1-methyl-1H-pyrazole-5-carbonyl chloride. The dihedral angles between the chlorobenzene and the two pyrazole rings are 59.8 (2) and 33.3&...

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Main Authors: Dehua Zhang, Xiaoyan Zhang, Lijuan Guo
Format: Article
Language:English
Published: International Union of Crystallography 2009-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809008988
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spelling doaj-755241e60f1c4307a52b70d9b45d608e2020-11-25T01:08:59ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-04-01654o887o88710.1107/S1600536809008988(Z)-Ethyl 3-[bis(4-chloro-3-ethyl-1-methyl-1H-pyrazol-5-ylcarbonyl)amino]-3-(4-chlorophenyl)-2-cyanopropanoateDehua ZhangXiaoyan ZhangLijuan GuoThe title compound, C26H25Cl3N6O4, was prepared by the reaction of (Z)-ethyl 3-amino-3-(4-chlorophenyl)-2-cyanoacrylate and 4-chloro-3-ethyl-1-methyl-1H-pyrazole-5-carbonyl chloride. The dihedral angles between the chlorobenzene and the two pyrazole rings are 59.8 (2) and 33.3 (2)°. The two pyrazole rings are oriented to each other at a dihedral angle of 84.7 (2)°. The crystal packing is governed by intermolecular C—H...O interactions, resulting in a three-dimensional network. The ethyl groups are disordered over two positions, with site-occupancy factors of 0.71/0.29 and 0.51/0.49. http://scripts.iucr.org/cgi-bin/paper?S1600536809008988
collection DOAJ
language English
format Article
sources DOAJ
author Dehua Zhang
Xiaoyan Zhang
Lijuan Guo
spellingShingle Dehua Zhang
Xiaoyan Zhang
Lijuan Guo
(Z)-Ethyl 3-[bis(4-chloro-3-ethyl-1-methyl-1H-pyrazol-5-ylcarbonyl)amino]-3-(4-chlorophenyl)-2-cyanopropanoate
Acta Crystallographica Section E
author_facet Dehua Zhang
Xiaoyan Zhang
Lijuan Guo
author_sort Dehua Zhang
title (Z)-Ethyl 3-[bis(4-chloro-3-ethyl-1-methyl-1H-pyrazol-5-ylcarbonyl)amino]-3-(4-chlorophenyl)-2-cyanopropanoate
title_short (Z)-Ethyl 3-[bis(4-chloro-3-ethyl-1-methyl-1H-pyrazol-5-ylcarbonyl)amino]-3-(4-chlorophenyl)-2-cyanopropanoate
title_full (Z)-Ethyl 3-[bis(4-chloro-3-ethyl-1-methyl-1H-pyrazol-5-ylcarbonyl)amino]-3-(4-chlorophenyl)-2-cyanopropanoate
title_fullStr (Z)-Ethyl 3-[bis(4-chloro-3-ethyl-1-methyl-1H-pyrazol-5-ylcarbonyl)amino]-3-(4-chlorophenyl)-2-cyanopropanoate
title_full_unstemmed (Z)-Ethyl 3-[bis(4-chloro-3-ethyl-1-methyl-1H-pyrazol-5-ylcarbonyl)amino]-3-(4-chlorophenyl)-2-cyanopropanoate
title_sort (z)-ethyl 3-[bis(4-chloro-3-ethyl-1-methyl-1h-pyrazol-5-ylcarbonyl)amino]-3-(4-chlorophenyl)-2-cyanopropanoate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-04-01
description The title compound, C26H25Cl3N6O4, was prepared by the reaction of (Z)-ethyl 3-amino-3-(4-chlorophenyl)-2-cyanoacrylate and 4-chloro-3-ethyl-1-methyl-1H-pyrazole-5-carbonyl chloride. The dihedral angles between the chlorobenzene and the two pyrazole rings are 59.8 (2) and 33.3 (2)°. The two pyrazole rings are oriented to each other at a dihedral angle of 84.7 (2)°. The crystal packing is governed by intermolecular C—H...O interactions, resulting in a three-dimensional network. The ethyl groups are disordered over two positions, with site-occupancy factors of 0.71/0.29 and 0.51/0.49.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809008988
work_keys_str_mv AT dehuazhang zethyl3bis4chloro3ethyl1methyl1hpyrazol5ylcarbonylamino34chlorophenyl2cyanopropanoate
AT xiaoyanzhang zethyl3bis4chloro3ethyl1methyl1hpyrazol5ylcarbonylamino34chlorophenyl2cyanopropanoate
AT lijuanguo zethyl3bis4chloro3ethyl1methyl1hpyrazol5ylcarbonylamino34chlorophenyl2cyanopropanoate
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