Carbon-13 composition of bulk dry wines by irm-EA/MS and irm-13C NMR: An indicator of vine water status

Measurements performed on a set of 32 authentic wines (not submitted to any oenological treatment) and their ethanol, recovered by distillation, show high correlation between δ13C of bulk wine and its ethanol. These measurements were performed by isotope ratio monitoring by mass spectrometry coupled...

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Bibliographic Details
Main Authors: Guyon Francois, Leeuwen Cornelis van, Gaillard Laetitia, Grand Mathilde, Akoka Serge, Remaud Gérald S., Sabathié Nathalie, Salagoïty Marie-Hélène
Format: Article
Language:English
Published: EDP Sciences 2017-01-01
Series:BIO Web of Conferences
Online Access:https://doi.org/10.1051/bioconf/20170902021
Description
Summary:Measurements performed on a set of 32 authentic wines (not submitted to any oenological treatment) and their ethanol, recovered by distillation, show high correlation between δ13C of bulk wine and its ethanol. These measurements were performed by isotope ratio monitoring by mass spectrometry coupled to an elemental analyzer (irm-EA/MS). Then a series of wines produced by vines of which water status was assessed during the growing season with predawn leaf water potential measurements, was studied by irm-EA/MS. As expected δ13C is correlated to vine water status conditions, as a result of stomatal closure. The ethanol of these specific wines was also analyzed by isotope ratio monitoring and by nuclear magnetic resonance (irm-13C NMR) to determine carbon-13 composition on the two specific sites of the ethanol skeleton. If these measurements confirm the correlation between 13C composition and vine growth conditions, the 13C stereospecific information does not make vine water status assessment more precise.
ISSN:2117-4458