(2E)-2-(5-Bromo-2-hydroxy-3-methoxybenzylidene)-N-phenylhydrazinecarbothioamide

(2E)-2-(5-Bromo-2-hydroxy-3-methoxybenzylidene)-N-phenylhydrazinecarbothioamide

The title compound, C15H14BrN3O2S, adopts an E,E conformation with respect to the azomethine and hydrazinic bonds and exists in the thioamide form. The two rings in the molecule are twisted away from each other, making a dihedral angle of 69.13 (13)°. In the crystal, molec...

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Main Authors: Jinsa Mary Jacob, M. Sithambaresan, M. R. Prathapachandra Kurup
Format: Article
Language:English
Published: International Union of Crystallography 2012-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812022520
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spelling doaj-74caf114369d44b9b669b09cdbfa3e432020-11-24T21:20:18ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-06-01686o1871o187210.1107/S1600536812022520(2E)-2-(5-Bromo-2-hydroxy-3-methoxybenzylidene)-N-phenylhydrazinecarbothioamideJinsa Mary JacobM. SithambaresanM. R. Prathapachandra KurupThe title compound, C15H14BrN3O2S, adopts an E,E conformation with respect to the azomethine and hydrazinic bonds and exists in the thioamide form. The two rings in the molecule are twisted away from each other, making a dihedral angle of 69.13 (13)°. In the crystal, molecules are linked through pairs of N—H...O and O—H...S hydrogen bonds, leading to the formation of inversion dimers which are stacked along the a axis. Intramolecular N—H...N, O—H...O and C—H...π interactions are also present.http://scripts.iucr.org/cgi-bin/paper?S1600536812022520
collection DOAJ
language English
format Article
sources DOAJ
author Jinsa Mary Jacob
M. Sithambaresan
M. R. Prathapachandra Kurup
spellingShingle Jinsa Mary Jacob
M. Sithambaresan
M. R. Prathapachandra Kurup
(2E)-2-(5-Bromo-2-hydroxy-3-methoxybenzylidene)-N-phenylhydrazinecarbothioamide
Acta Crystallographica Section E
author_facet Jinsa Mary Jacob
M. Sithambaresan
M. R. Prathapachandra Kurup
author_sort Jinsa Mary Jacob
title (2E)-2-(5-Bromo-2-hydroxy-3-methoxybenzylidene)-N-phenylhydrazinecarbothioamide
title_short (2E)-2-(5-Bromo-2-hydroxy-3-methoxybenzylidene)-N-phenylhydrazinecarbothioamide
title_full (2E)-2-(5-Bromo-2-hydroxy-3-methoxybenzylidene)-N-phenylhydrazinecarbothioamide
title_fullStr (2E)-2-(5-Bromo-2-hydroxy-3-methoxybenzylidene)-N-phenylhydrazinecarbothioamide
title_full_unstemmed (2E)-2-(5-Bromo-2-hydroxy-3-methoxybenzylidene)-N-phenylhydrazinecarbothioamide
title_sort (2e)-2-(5-bromo-2-hydroxy-3-methoxybenzylidene)-n-phenylhydrazinecarbothioamide
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-06-01
description The title compound, C15H14BrN3O2S, adopts an E,E conformation with respect to the azomethine and hydrazinic bonds and exists in the thioamide form. The two rings in the molecule are twisted away from each other, making a dihedral angle of 69.13 (13)°. In the crystal, molecules are linked through pairs of N—H...O and O—H...S hydrogen bonds, leading to the formation of inversion dimers which are stacked along the a axis. Intramolecular N—H...N, O—H...O and C—H...π interactions are also present.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812022520
work_keys_str_mv AT jinsamaryjacob 2e25bromo2hydroxy3methoxybenzylidenenphenylhydrazinecarbothioamide
AT msithambaresan 2e25bromo2hydroxy3methoxybenzylidenenphenylhydrazinecarbothioamide
AT mrprathapachandrakurup 2e25bromo2hydroxy3methoxybenzylidenenphenylhydrazinecarbothioamide
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