Photocatalysis with organic dyes: facile access to reactive intermediates for synthesis

Organic dyes have emerged as a reliable class of photoredox catalysts. Their great structural variety combined with the easy fine-tuning of their electronic properties has unlocked new possibilities for the generation of reactive intermediates. In this review, we provide an overview of the available...

Full description

Bibliographic Details
Main Authors:	Stephanie G. E. Amos, Marion Garreau, Luca Buzzetti, Jerome Waser
Format:	Article
Language:	English
Published:	Beilstein-Institut 2020-05-01
Series:	Beilstein Journal of Organic Chemistry
Subjects:	organic dyes photocatalysis photoredox catalysis radicals reactive intermediates
Online Access:	https://doi.org/10.3762/bjoc.16.103

id	doaj-743bb2c182254b1c8d49c8288908fb5e
record_format	Article
spelling	doaj-743bb2c182254b1c8d49c8288908fb5e2021-04-02T15:49:19ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972020-05-011611163118710.3762/bjoc.16.1031860-5397-16-103Photocatalysis with organic dyes: facile access to reactive intermediates for synthesisStephanie G. E. Amos0Marion Garreau1Luca Buzzetti2Jerome Waser3Laboratory of Catalysis and Organic Synthesis, Ecole Polytechnique Fédérale de Lausanne, EPFL, SB ISIC LCSO, BCH 4306 1015 Lausanne, SwitzerlandLaboratory of Catalysis and Organic Synthesis, Ecole Polytechnique Fédérale de Lausanne, EPFL, SB ISIC LCSO, BCH 4306 1015 Lausanne, SwitzerlandLaboratory of Catalysis and Organic Synthesis, Ecole Polytechnique Fédérale de Lausanne, EPFL, SB ISIC LCSO, BCH 4306 1015 Lausanne, SwitzerlandLaboratory of Catalysis and Organic Synthesis, Ecole Polytechnique Fédérale de Lausanne, EPFL, SB ISIC LCSO, BCH 4306 1015 Lausanne, SwitzerlandOrganic dyes have emerged as a reliable class of photoredox catalysts. Their great structural variety combined with the easy fine-tuning of their electronic properties has unlocked new possibilities for the generation of reactive intermediates. In this review, we provide an overview of the available approaches to access reactive intermediates that employ organophotocatalysis. Our contribution is not a comprehensive description of the work in the area but rather focuses on key concepts, accompanied by a few selected illustrative examples. The review is organized along the type of reactive intermediates formed in the reaction, including C(sp3) and C(sp2) carbon-, nitrogen-, oxygen-, and sulfur-centered radicals, open-shell charged species, and sensitized organic compounds.https://doi.org/10.3762/bjoc.16.103organic dyesphotocatalysisphotoredox catalysisradicalsreactive intermediates
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Stephanie G. E. Amos Marion Garreau Luca Buzzetti Jerome Waser
spellingShingle	Stephanie G. E. Amos Marion Garreau Luca Buzzetti Jerome Waser Photocatalysis with organic dyes: facile access to reactive intermediates for synthesis Beilstein Journal of Organic Chemistry organic dyes photocatalysis photoredox catalysis radicals reactive intermediates
author_facet	Stephanie G. E. Amos Marion Garreau Luca Buzzetti Jerome Waser
author_sort	Stephanie G. E. Amos
title	Photocatalysis with organic dyes: facile access to reactive intermediates for synthesis
title_short	Photocatalysis with organic dyes: facile access to reactive intermediates for synthesis
title_full	Photocatalysis with organic dyes: facile access to reactive intermediates for synthesis
title_fullStr	Photocatalysis with organic dyes: facile access to reactive intermediates for synthesis
title_full_unstemmed	Photocatalysis with organic dyes: facile access to reactive intermediates for synthesis
title_sort	photocatalysis with organic dyes: facile access to reactive intermediates for synthesis
publisher	Beilstein-Institut
series	Beilstein Journal of Organic Chemistry
issn	1860-5397
publishDate	2020-05-01
description	Organic dyes have emerged as a reliable class of photoredox catalysts. Their great structural variety combined with the easy fine-tuning of their electronic properties has unlocked new possibilities for the generation of reactive intermediates. In this review, we provide an overview of the available approaches to access reactive intermediates that employ organophotocatalysis. Our contribution is not a comprehensive description of the work in the area but rather focuses on key concepts, accompanied by a few selected illustrative examples. The review is organized along the type of reactive intermediates formed in the reaction, including C(sp3) and C(sp2) carbon-, nitrogen-, oxygen-, and sulfur-centered radicals, open-shell charged species, and sensitized organic compounds.
topic	organic dyes photocatalysis photoredox catalysis radicals reactive intermediates
url	https://doi.org/10.3762/bjoc.16.103
work_keys_str_mv	AT stephaniegeamos photocatalysiswithorganicdyesfacileaccesstoreactiveintermediatesforsynthesis AT mariongarreau photocatalysiswithorganicdyesfacileaccesstoreactiveintermediatesforsynthesis AT lucabuzzetti photocatalysiswithorganicdyesfacileaccesstoreactiveintermediatesforsynthesis AT jeromewaser photocatalysiswithorganicdyesfacileaccesstoreactiveintermediatesforsynthesis
_version_	1721559024033333248

Photocatalysis with organic dyes: facile access to reactive intermediates for synthesis

Similar Items