An indenide-tethered N-heterocyclic stannylene

An indenide-tethered N-heterocyclic stannylene

The structure of (μ-1κN:2(η2),κ2N,N′-(2-{[2,6-bis(propan-2-yl)phenyl]azanidyl}ethyl)[2-(1H-inden-1-yl)ethyl]azanido)(1,4,7,10,13,16-hexaoxacyclooctadecane-1κ6O)lithiumtin, [LiSn(C8H16O4)(C25H31N2)], at 100 K has monoclinic (P21/n) symmetry. Analysis of the coordination of the Sn to the indenyl ring...

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Bibliographic Details
Main Authors: Tobias Bischof, Kieren J. Evans, Mairi F. Haddow, Stephen M. Mansell
Format: Article
Language:English
Published: International Union of Crystallography 2020-02-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
stannylene
η-2 coordination
indenyl donor group
Online Access:http://scripts.iucr.org/cgi-bin/paper?S205698902000047X
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spelling doaj-73bc66e2dcdd4bc2a1d798b5b536c5102020-11-25T03:34:59ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902020-02-0176225425610.1107/S205698902000047Xff2165An indenide-tethered N-heterocyclic stannyleneTobias Bischof0Kieren J. Evans1Mairi F. Haddow2Stephen M. Mansell3Institute of Chemical Sciences, School of Engineering and Physical Sciences, Heriot-Watt University, Edinburgh, EH14 4AS, ScotlandInstitute of Chemical Sciences, School of Engineering and Physical Sciences, Heriot-Watt University, Edinburgh, EH14 4AS, ScotlandInstitute of Chemical Sciences, School of Engineering and Physical Sciences, Heriot-Watt University, Edinburgh, EH14 4AS, ScotlandInstitute of Chemical Sciences, School of Engineering and Physical Sciences, Heriot-Watt University, Edinburgh, EH14 4AS, ScotlandThe structure of (μ-1κN:2(η2),κ2N,N′-(2-{[2,6-bis(propan-2-yl)phenyl]azanidyl}ethyl)[2-(1H-inden-1-yl)ethyl]azanido)(1,4,7,10,13,16-hexaoxacyclooctadecane-1κ6O)lithiumtin, [LiSn(C8H16O4)(C25H31N2)], at 100 K has monoclinic (P21/n) symmetry. Analysis of the coordination of the Sn to the indenyl ring shows that the Sn interacts in an η2 fashion. A database survey showed that whilst this coordination mode is unusual for Ge and Pb compounds, Sn displays a wider range of coordination modes to cyclopentadienyl ligands and their derivatives.http://scripts.iucr.org/cgi-bin/paper?S205698902000047Xcrystal structurestannyleneη-2 coordinationindenyl donor group
collection DOAJ
language English
format Article
sources DOAJ
author Tobias Bischof
Kieren J. Evans
Mairi F. Haddow
Stephen M. Mansell
spellingShingle Tobias Bischof
Kieren J. Evans
Mairi F. Haddow
Stephen M. Mansell
An indenide-tethered N-heterocyclic stannylene
Acta Crystallographica Section E: Crystallographic Communications
crystal structure
stannylene
η-2 coordination
indenyl donor group
author_facet Tobias Bischof
Kieren J. Evans
Mairi F. Haddow
Stephen M. Mansell
author_sort Tobias Bischof
title An indenide-tethered N-heterocyclic stannylene
title_short An indenide-tethered N-heterocyclic stannylene
title_full An indenide-tethered N-heterocyclic stannylene
title_fullStr An indenide-tethered N-heterocyclic stannylene
title_full_unstemmed An indenide-tethered N-heterocyclic stannylene
title_sort indenide-tethered n-heterocyclic stannylene
publisher International Union of Crystallography
series Acta Crystallographica Section E: Crystallographic Communications
issn 2056-9890
publishDate 2020-02-01
description The structure of (μ-1κN:2(η2),κ2N,N′-(2-{[2,6-bis(propan-2-yl)phenyl]azanidyl}ethyl)[2-(1H-inden-1-yl)ethyl]azanido)(1,4,7,10,13,16-hexaoxacyclooctadecane-1κ6O)lithiumtin, [LiSn(C8H16O4)(C25H31N2)], at 100 K has monoclinic (P21/n) symmetry. Analysis of the coordination of the Sn to the indenyl ring shows that the Sn interacts in an η2 fashion. A database survey showed that whilst this coordination mode is unusual for Ge and Pb compounds, Sn displays a wider range of coordination modes to cyclopentadienyl ligands and their derivatives.
topic crystal structure
stannylene
η-2 coordination
indenyl donor group
url http://scripts.iucr.org/cgi-bin/paper?S205698902000047X
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