MW-Promoted Cu(I)-Catalyzed P–C Coupling Reactions without the Addition of Conventional Ligands; an Experimental and a Theoretical Study

MW-Promoted Cu(I)-Catalyzed P–C Coupling Reactions without the Addition of Conventional Ligands; an Experimental and a Theoretical Study

An experimental and a theoretical study on the so far less investigated Cu(I) salt-catalyzed Hirao reaction of iodobenzene and diarylphosphine oxides (DAPOs) revealed that Cu(I)Br or Cu(I)Cl is the most efficient catalyst under microwave irradiation. The optimum conditions included 165 °C and a 1:2...

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Bibliographic Details
Main Authors: Bianka Huszár, Réka Henyecz, Zoltán Mucsi, György Keglevich
Format: Article
Language:English
Published: MDPI AG 2021-07-01
Series:Catalysts
Subjects:
Hirao reaction
copper(I) catalyst
microwave
tertiary phosphine oxide
theoretical calculations
ligation
Online Access:https://www.mdpi.com/2073-4344/11/8/933

Internet

https://www.mdpi.com/2073-4344/11/8/933

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