Pressure-Related Universal Previtreous Behavior of the Structural Relaxation Time and Apparent Fragility

The report presents the evidence for the hypothetically “universal” previtreous behavior of the pressure related apparent fragility: mT(P)∞1/(P*-P), where P* is the extrapolated singular pressure. This finding was the basis for deriving the “model-free” dependence for the pressure evolution of the s...

Full description

Bibliographic Details
Main Author: Aleksandra Drozd-Rzoska
Format: Article
Language:English
Published: Frontiers Media S.A. 2019-05-01
Series:Frontiers in Materials
Subjects:
Online Access:https://www.frontiersin.org/article/10.3389/fmats.2019.00103/full
Description
Summary:The report presents the evidence for the hypothetically “universal” previtreous behavior of the pressure related apparent fragility: mT(P)∞1/(P*-P), where P* is the extrapolated singular pressure. This finding was the basis for deriving the “model-free” dependence for the pressure evolution of the structural relaxation time: τ(P)=τoP(P*-P)-Ψ. All these led to the new way of testing the dynamic crossover phenomenon via 1/mT (P) vs. P plot. Finally, the behavior of electric conductivity in the previtreous domain is discussed. The experimental evidence covers 8*OCB (liquid crystal), EPON 828 (resin), diisobutyl phthalate, and propylene carbonate (low molecular weight liquids). Experiments were carried up to extreme P~ 2.2 GPa, in the “bulk” measurement capacitor. This report also contains a summary of existing descriptions of the pressure evolution of structural relaxation time or viscosity on approaching the glass transition.
ISSN:2296-8016