Effective Improving the Detection Limit of Tris(2,3-dibromopropyl) Isocyanurate by Bis-amino in O-phenylenediamine

Effective Improving the Detection Limit of Tris(2,3-dibromopropyl) Isocyanurate by Bis-amino in O-phenylenediamine

A facile approach for ultrasensitively sensing tris(2,3-dibromopropyl) isocyanurate (TBC) was reported. Based on coupling molecularly imprinting with electropolymerization of ο-phenylenediamine (OPD), which is electro-active monomers, the poly-OPD film was deposited in an OPD solution by potentiodyn...

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Main Authors: Huang Limei, Li Meishan, Wu Dan, Liu Jiaxiang, Ma Xiuling
Format: Article
Language:English
Published: EDP Sciences 2016-01-01
Series:MATEC Web of Conferences
Online Access:http://dx.doi.org/10.1051/matecconf/20166706092
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spelling doaj-7351af85752d41588613d3e2be779f972021-02-02T04:27:29ZengEDP SciencesMATEC Web of Conferences2261-236X2016-01-01670609210.1051/matecconf/20166706092matecconf_smae2016_06092Effective Improving the Detection Limit of Tris(2,3-dibromopropyl) Isocyanurate by Bis-amino in O-phenylenediamineHuang Limei0Li Meishan1Wu Dan2Liu Jiaxiang3Ma Xiuling4College of Chemistry and Chemical Engineering, Fujian Normal UniversityCollege of Chemistry and Chemical Engineering, Fujian Normal UniversityCollege of Chemistry and Chemical Engineering, Fujian Normal UniversityCollege of Chemistry and Chemical Engineering, Fujian Normal UniversityCollege of Chemistry and Chemical Engineering, Fujian Normal UniversityA facile approach for ultrasensitively sensing tris(2,3-dibromopropyl) isocyanurate (TBC) was reported. Based on coupling molecularly imprinting with electropolymerization of ο-phenylenediamine (OPD), which is electro-active monomers, the poly-OPD film was deposited in an OPD solution by potentiodynamic cycling of potential (scan rate is 50mV/s) on a glassy carbon electrode. Using K3[Fe(CN)6] as an electro-active marker, the properties of the TBC imprinting electrode were investigated by differential pulse voltammetry and amperometric i-t curve and exhibited an excellent imprinting effect. The results showed that a linear relationship between the value of peak current and the TBC concentration was found in the range of 1.4×10−12~6.7×10−12 mol/L and a low detection limit of 6.26×10−13 mol/L for TBC determination.http://dx.doi.org/10.1051/matecconf/20166706092
collection DOAJ
language English
format Article
sources DOAJ
author Huang Limei
Li Meishan
Wu Dan
Liu Jiaxiang
Ma Xiuling
spellingShingle Huang Limei
Li Meishan
Wu Dan
Liu Jiaxiang
Ma Xiuling
Effective Improving the Detection Limit of Tris(2,3-dibromopropyl) Isocyanurate by Bis-amino in O-phenylenediamine
MATEC Web of Conferences
author_facet Huang Limei
Li Meishan
Wu Dan
Liu Jiaxiang
Ma Xiuling
author_sort Huang Limei
title Effective Improving the Detection Limit of Tris(2,3-dibromopropyl) Isocyanurate by Bis-amino in O-phenylenediamine
title_short Effective Improving the Detection Limit of Tris(2,3-dibromopropyl) Isocyanurate by Bis-amino in O-phenylenediamine
title_full Effective Improving the Detection Limit of Tris(2,3-dibromopropyl) Isocyanurate by Bis-amino in O-phenylenediamine
title_fullStr Effective Improving the Detection Limit of Tris(2,3-dibromopropyl) Isocyanurate by Bis-amino in O-phenylenediamine
title_full_unstemmed Effective Improving the Detection Limit of Tris(2,3-dibromopropyl) Isocyanurate by Bis-amino in O-phenylenediamine
title_sort effective improving the detection limit of tris(2,3-dibromopropyl) isocyanurate by bis-amino in o-phenylenediamine
publisher EDP Sciences
series MATEC Web of Conferences
issn 2261-236X
publishDate 2016-01-01
description A facile approach for ultrasensitively sensing tris(2,3-dibromopropyl) isocyanurate (TBC) was reported. Based on coupling molecularly imprinting with electropolymerization of ο-phenylenediamine (OPD), which is electro-active monomers, the poly-OPD film was deposited in an OPD solution by potentiodynamic cycling of potential (scan rate is 50mV/s) on a glassy carbon electrode. Using K3[Fe(CN)6] as an electro-active marker, the properties of the TBC imprinting electrode were investigated by differential pulse voltammetry and amperometric i-t curve and exhibited an excellent imprinting effect. The results showed that a linear relationship between the value of peak current and the TBC concentration was found in the range of 1.4×10−12~6.7×10−12 mol/L and a low detection limit of 6.26×10−13 mol/L for TBC determination.
url http://dx.doi.org/10.1051/matecconf/20166706092
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AT limeishan effectiveimprovingthedetectionlimitoftris23dibromopropylisocyanuratebybisaminoinophenylenediamine
AT wudan effectiveimprovingthedetectionlimitoftris23dibromopropylisocyanuratebybisaminoinophenylenediamine
AT liujiaxiang effectiveimprovingthedetectionlimitoftris23dibromopropylisocyanuratebybisaminoinophenylenediamine
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