Synthesis of C7-C16-alkyl maltosides in the presence of tin(IV) chloride as a Lewis acid catalyst

The synthesis of C7- to C16-alkyl maltosides in the presence of tin(IV) chloride as Lewis acid catalyst was performed. The characterization of the products and theoretical investigation of the crucial step in the synthesis were carried out. The preparation of the β-maltosides required reaction time...

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Main Authors:	Zoran Marković, Jasmina Predojevic, Nedeljko T. Manojlovic
Format:	Article
Language:	English
Published:	Chemical Society of Ethiopia 2011-04-01
Series:	Bulletin of the Chemical Society of Ethiopia
Subjects:	Maltose Synthesis of maltosides Tin(IV) chloride PM3
Online Access:	http://ajol.info/index.php/bcse/article/view/63368

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spelling	doaj-7330977ea542479e80e0de1f1f7726502020-11-24T23:16:30ZengChemical Society of EthiopiaBulletin of the Chemical Society of Ethiopia1011-39241726-801X2011-04-012518390<b>Synthesis of C<sub>7</sub>-C<sub>16</sub>-alkyl maltosides in the presence of tin(IV) chloride as a Lewis acid catalyst</b>Zoran MarkovićJasmina PredojevicNedeljko T. ManojlovicThe synthesis of C7- to C16-alkyl maltosides in the presence of tin(IV) chloride as Lewis acid catalyst was performed. The characterization of the products and theoretical investigation of the crucial step in the synthesis were carried out. The preparation of the β-maltosides required reaction time of 1 h, and that of the α-maltosides was 72 h. The side products were the α-D-maltosidechloride and 2-hydroxy-β-maltoside, respectively. The PM3 calculation confirmed the formation of the kinetically controlled β-product.http://ajol.info/index.php/bcse/article/view/63368MaltoseSynthesis of maltosidesTin(IV) chloridePM3
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Zoran Marković Jasmina Predojevic Nedeljko T. Manojlovic
spellingShingle	Zoran Marković Jasmina Predojevic Nedeljko T. Manojlovic <b>Synthesis of C<sub>7</sub>-C<sub>16</sub>-alkyl maltosides in the presence of tin(IV) chloride as a Lewis acid catalyst</b> Bulletin of the Chemical Society of Ethiopia Maltose Synthesis of maltosides Tin(IV) chloride PM3
author_facet	Zoran Marković Jasmina Predojevic Nedeljko T. Manojlovic
author_sort	Zoran Marković
title	<b>Synthesis of C<sub>7</sub>-C<sub>16</sub>-alkyl maltosides in the presence of tin(IV) chloride as a Lewis acid catalyst</b>
title_short	<b>Synthesis of C<sub>7</sub>-C<sub>16</sub>-alkyl maltosides in the presence of tin(IV) chloride as a Lewis acid catalyst</b>
title_full	<b>Synthesis of C<sub>7</sub>-C<sub>16</sub>-alkyl maltosides in the presence of tin(IV) chloride as a Lewis acid catalyst</b>
title_fullStr	<b>Synthesis of C<sub>7</sub>-C<sub>16</sub>-alkyl maltosides in the presence of tin(IV) chloride as a Lewis acid catalyst</b>
title_full_unstemmed	<b>Synthesis of C<sub>7</sub>-C<sub>16</sub>-alkyl maltosides in the presence of tin(IV) chloride as a Lewis acid catalyst</b>
title_sort	<b>synthesis of c<sub>7</sub>-c<sub>16</sub>-alkyl maltosides in the presence of tin(iv) chloride as a lewis acid catalyst</b>
publisher	Chemical Society of Ethiopia
series	Bulletin of the Chemical Society of Ethiopia
issn	1011-3924 1726-801X
publishDate	2011-04-01
description	The synthesis of C7- to C16-alkyl maltosides in the presence of tin(IV) chloride as Lewis acid catalyst was performed. The characterization of the products and theoretical investigation of the crucial step in the synthesis were carried out. The preparation of the β-maltosides required reaction time of 1 h, and that of the α-maltosides was 72 h. The side products were the α-D-maltosidechloride and 2-hydroxy-β-maltoside, respectively. The PM3 calculation confirmed the formation of the kinetically controlled β-product.
topic	Maltose Synthesis of maltosides Tin(IV) chloride PM3
url	http://ajol.info/index.php/bcse/article/view/63368
work_keys_str_mv	AT zoranmarkovic bsynthesisofcsub7subcsub16subalkylmaltosidesinthepresenceoftinivchlorideasalewisacidcatalystb AT jasminapredojevic bsynthesisofcsub7subcsub16subalkylmaltosidesinthepresenceoftinivchlorideasalewisacidcatalystb AT nedeljkotmanojlovic bsynthesisofcsub7subcsub16subalkylmaltosidesinthepresenceoftinivchlorideasalewisacidcatalystb
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<b>Synthesis of C<sub>7</sub>-C<sub>16</sub>-alkyl maltosides in the presence of tin(IV) chloride as a Lewis acid catalyst</b>

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