Reference-Electrode Free pH Sensing Using Impedance Spectroscopy

We present a reference-electrode free sensor able to measure both pH and conductivity<br />based on impedance spectroscopy. The electrode is made of a layer of indium-tin-oxide (ITO). The<br />impedance of this electrode at low frequencies depends on its double layer capacity, which vari...

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Bibliographic Details
Main Authors: Laura Folkertsma, Lennart Gehrenkemper, Jan Eijkel, Karin Gerritsen, Mathieu Odijk
Format: Article
Language:English
Published: MDPI AG 2018-11-01
Series:Proceedings
Subjects:
Online Access:https://www.mdpi.com/2504-3900/2/13/742
Description
Summary:We present a reference-electrode free sensor able to measure both pH and conductivity<br />based on impedance spectroscopy. The electrode is made of a layer of indium-tin-oxide (ITO). The<br />impedance of this electrode at low frequencies depends on its double layer capacity, which varies<br />with pH due to modification of oxide groups at the ITO surface. At high frequencies, the impedance<br />is determined by the resistance in the system, which corresponds to the inverse conductivity of the<br />solution. Because no reference electrode is needed for this technique, miniaturization of the pH<br />sensor is simple. We demonstrate a proof-of-principle experiment of the sensor for human plasma<br />pH measurements.
ISSN:2504-3900