Copolymerization of Phenylselenide-Substituted Maleimide with Styrene and Its Oxidative Elimination Behavior

Copolymerization of Phenylselenide-Substituted Maleimide with Styrene and Its Oxidative Elimination Behavior

Selenium-containing monomer monophenyl maleimide selenide (MSM) was synthesized and copolymerized with styrene (St) using reversible addition-fragmentation chain transfer (RAFT) polymerization. Copolymers with controlled molecular weight and narrow molecular weight distribution were obtained. The st...

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Main Authors: Qian Liu, Xinghua Lv, Na Li, Xiangqiang Pan, Jian Zhu, Xiulin Zhu
Format: Article
Language:English
Published: MDPI AG 2018-03-01
Series:Polymers
Subjects:
selenium-containing monomer
reversible addition-fragmentation chain transfer (RAFT)
oxidation
carbon-carbon double bond
Online Access:http://www.mdpi.com/2073-4360/10/3/321
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spelling doaj-72169d54650f4ca081708d170b7f0ac82020-11-25T00:05:05ZengMDPI AGPolymers2073-43602018-03-0110332110.3390/polym10030321polym10030321Copolymerization of Phenylselenide-Substituted Maleimide with Styrene and Its Oxidative Elimination BehaviorQian Liu0Xinghua Lv1Na Li2Xiangqiang Pan3Jian Zhu4Xiulin Zhu5State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, ChinaState and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, ChinaState and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, ChinaState and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, ChinaState and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, ChinaState and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, ChinaSelenium-containing monomer monophenyl maleimide selenide (MSM) was synthesized and copolymerized with styrene (St) using reversible addition-fragmentation chain transfer (RAFT) polymerization. Copolymers with controlled molecular weight and narrow molecular weight distribution were obtained. The structure of the copolymer was characterized by nuclear magnetic resonance, matrix-assisted laser desorption/ionization time-of-flight (MALDI-TOF) mass spectrum, Fourier transform infrared spectroscopy (FT-IR) and Ultraviolet–visible spectroscopy (UV-vis) spectroscopy. The copolymer can be oxidized by H2O2 to form carbon-carbon double bonds within the main chain due to the unique sensitivity of selenide groups in the presence of oxidants. Such structure changing resulted in an interesting concentration-related photoluminescence emission enhancement.http://www.mdpi.com/2073-4360/10/3/321selenium-containing monomerreversible addition-fragmentation chain transfer (RAFT)oxidationcarbon-carbon double bond
collection DOAJ
language English
format Article
sources DOAJ
author Qian Liu
Xinghua Lv
Na Li
Xiangqiang Pan
Jian Zhu
Xiulin Zhu
spellingShingle Qian Liu
Xinghua Lv
Na Li
Xiangqiang Pan
Jian Zhu
Xiulin Zhu
Copolymerization of Phenylselenide-Substituted Maleimide with Styrene and Its Oxidative Elimination Behavior
Polymers
selenium-containing monomer
reversible addition-fragmentation chain transfer (RAFT)
oxidation
carbon-carbon double bond
author_facet Qian Liu
Xinghua Lv
Na Li
Xiangqiang Pan
Jian Zhu
Xiulin Zhu
author_sort Qian Liu
title Copolymerization of Phenylselenide-Substituted Maleimide with Styrene and Its Oxidative Elimination Behavior
title_short Copolymerization of Phenylselenide-Substituted Maleimide with Styrene and Its Oxidative Elimination Behavior
title_full Copolymerization of Phenylselenide-Substituted Maleimide with Styrene and Its Oxidative Elimination Behavior
title_fullStr Copolymerization of Phenylselenide-Substituted Maleimide with Styrene and Its Oxidative Elimination Behavior
title_full_unstemmed Copolymerization of Phenylselenide-Substituted Maleimide with Styrene and Its Oxidative Elimination Behavior
title_sort copolymerization of phenylselenide-substituted maleimide with styrene and its oxidative elimination behavior
publisher MDPI AG
series Polymers
issn 2073-4360
publishDate 2018-03-01
description Selenium-containing monomer monophenyl maleimide selenide (MSM) was synthesized and copolymerized with styrene (St) using reversible addition-fragmentation chain transfer (RAFT) polymerization. Copolymers with controlled molecular weight and narrow molecular weight distribution were obtained. The structure of the copolymer was characterized by nuclear magnetic resonance, matrix-assisted laser desorption/ionization time-of-flight (MALDI-TOF) mass spectrum, Fourier transform infrared spectroscopy (FT-IR) and Ultraviolet–visible spectroscopy (UV-vis) spectroscopy. The copolymer can be oxidized by H2O2 to form carbon-carbon double bonds within the main chain due to the unique sensitivity of selenide groups in the presence of oxidants. Such structure changing resulted in an interesting concentration-related photoluminescence emission enhancement.
topic selenium-containing monomer
reversible addition-fragmentation chain transfer (RAFT)
oxidation
carbon-carbon double bond
url http://www.mdpi.com/2073-4360/10/3/321
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AT xinghualv copolymerizationofphenylselenidesubstitutedmaleimidewithstyreneanditsoxidativeeliminationbehavior
AT nali copolymerizationofphenylselenidesubstitutedmaleimidewithstyreneanditsoxidativeeliminationbehavior
AT xiangqiangpan copolymerizationofphenylselenidesubstitutedmaleimidewithstyreneanditsoxidativeeliminationbehavior
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