Bis[4-(2-carbamoylhydrazin-1-ylidene-κ2N1,O)-5-hydroxymethyl-2-methylpyridinium-3-olato-κO3]cobalt(II) dinitrate dihydrate

Bis[4-(2-carbamoylhydrazin-1-ylidene-κ2N1,O)-5-hydroxymethyl-2-methylpyridinium-3-olato-κO3]cobalt(II) dinitrate dihydrate

The asymmetric unit of the title compound, [Co(C9H12N4O3)2](NO3)2·2H2O, consists of a discrete cationic [Co(PLSC)2]2+ complex unit [PLSC is 4-(2-carbamoylhydrazin-1-ylidene)-5-hydroxymethyl-2-methylpyridinium-3-olato], two NO3− and two water molecules. The two tridentate P...

Full description

Bibliographic Details
Main Authors: Dragoslav Vidovic, Violeta Jevtovic
Format: Article
Language:English
Published: International Union of Crystallography 2010-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810003570
id doaj-7206afc7dafc4cbfb240f9c2c7af8687
record_format Article
spelling doaj-7206afc7dafc4cbfb240f9c2c7af86872020-11-24T21:44:31ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-04-01664m408m40910.1107/S1600536810003570Bis[4-(2-carbamoylhydrazin-1-ylidene-κ2N1,O)-5-hydroxymethyl-2-methylpyridinium-3-olato-κO3]cobalt(II) dinitrate dihydrateDragoslav VidovicVioleta JevtovicThe asymmetric unit of the title compound, [Co(C9H12N4O3)2](NO3)2·2H2O, consists of a discrete cationic [Co(PLSC)2]2+ complex unit [PLSC is 4-(2-carbamoylhydrazin-1-ylidene)-5-hydroxymethyl-2-methylpyridinium-3-olato], two NO3− and two water molecules. The two tridentate PLSC ligands of the cation are zwitterions related to each other by a non-crystallographic C2 axis. The CoII ion is in a disorted octahedral coordination environment. The crystal structure is composed of alternating NO3/H2O and complex layers supported by extensive C—H...O, N—H...O and N—H...N hydrogen bonding. http://scripts.iucr.org/cgi-bin/paper?S1600536810003570
collection DOAJ
language English
format Article
sources DOAJ
author Dragoslav Vidovic
Violeta Jevtovic
spellingShingle Dragoslav Vidovic
Violeta Jevtovic
Bis[4-(2-carbamoylhydrazin-1-ylidene-κ2N1,O)-5-hydroxymethyl-2-methylpyridinium-3-olato-κO3]cobalt(II) dinitrate dihydrate
Acta Crystallographica Section E
author_facet Dragoslav Vidovic
Violeta Jevtovic
author_sort Dragoslav Vidovic
title Bis[4-(2-carbamoylhydrazin-1-ylidene-κ2N1,O)-5-hydroxymethyl-2-methylpyridinium-3-olato-κO3]cobalt(II) dinitrate dihydrate
title_short Bis[4-(2-carbamoylhydrazin-1-ylidene-κ2N1,O)-5-hydroxymethyl-2-methylpyridinium-3-olato-κO3]cobalt(II) dinitrate dihydrate
title_full Bis[4-(2-carbamoylhydrazin-1-ylidene-κ2N1,O)-5-hydroxymethyl-2-methylpyridinium-3-olato-κO3]cobalt(II) dinitrate dihydrate
title_fullStr Bis[4-(2-carbamoylhydrazin-1-ylidene-κ2N1,O)-5-hydroxymethyl-2-methylpyridinium-3-olato-κO3]cobalt(II) dinitrate dihydrate
title_full_unstemmed Bis[4-(2-carbamoylhydrazin-1-ylidene-κ2N1,O)-5-hydroxymethyl-2-methylpyridinium-3-olato-κO3]cobalt(II) dinitrate dihydrate
title_sort bis[4-(2-carbamoylhydrazin-1-ylidene-κ2n1,o)-5-hydroxymethyl-2-methylpyridinium-3-olato-κo3]cobalt(ii) dinitrate dihydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-04-01
description The asymmetric unit of the title compound, [Co(C9H12N4O3)2](NO3)2·2H2O, consists of a discrete cationic [Co(PLSC)2]2+ complex unit [PLSC is 4-(2-carbamoylhydrazin-1-ylidene)-5-hydroxymethyl-2-methylpyridinium-3-olato], two NO3− and two water molecules. The two tridentate PLSC ligands of the cation are zwitterions related to each other by a non-crystallographic C2 axis. The CoII ion is in a disorted octahedral coordination environment. The crystal structure is composed of alternating NO3/H2O and complex layers supported by extensive C—H...O, N—H...O and N—H...N hydrogen bonding.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810003570
work_keys_str_mv AT dragoslavvidovic bis42carbamoylhydrazin1ylideneamp9542n1o5hydroxymethyl2methylpyridinium3olatoamp954o3cobaltiidinitratedihydrate
AT violetajevtovic bis42carbamoylhydrazin1ylideneamp9542n1o5hydroxymethyl2methylpyridinium3olatoamp954o3cobaltiidinitratedihydrate
_version_ 1725909749482913792

Similar Items