Crystal structure of a rare trigonal bipyramidal titanium(IV) coordination complex: trichlorido(3,3′-di-tert-butyl-2′-hydroxy-5,5′,6,6′-tetramethyl-1,1′-biphenyl-2-olato-κO2)(tetrahydrofuran-κO)titanium(IV)

Crystal structure of a rare trigonal bipyramidal titanium(IV) coordination complex: trichlorido(3,3′-di-tert-butyl-2′-hydroxy-5,5′,6,6′-tetramethyl-1,1′-biphenyl-2-olato-κO2)(tetrahydrofuran-κO)titanium(IV)

The title compound, [Ti(C24H33O2)Cl3(C4H8O)], is a rare example of a trigonal–bipyramidal titanium coordination complex with three chloride and two oxygen donor ligands. The asymmetric unit contains two independent molecules having essentially the same conformation. The molecules feature the titaniu...

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Bibliographic Details
Main Authors: Yun Young Kim, Joseph M. Tanski
Format: Article
Language:English
Published: International Union of Crystallography 2017-01-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
coordination complex
titanium in trigonal–bipyramidal coordination
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989016020156

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