Crystal structure of a rare trigonal bipyramidal titanium(IV) coordination complex: trichlorido(3,3′-di-tert-butyl-2′-hydroxy-5,5′,6,6′-tetramethyl-1,1′-biphenyl-2-olato-κO2)(tetrahydrofuran-κO)titanium(IV)

The title compound, [Ti(C24H33O2)Cl3(C4H8O)], is a rare example of a trigonal–bipyramidal titanium coordination complex with three chloride and two oxygen donor ligands. The asymmetric unit contains two independent molecules having essentially the same conformation. The molecules feature the titaniu...

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Main Authors:	Yun Young Kim, Joseph M. Tanski
Format:	Article
Language:	English
Published:	International Union of Crystallography 2017-01-01
Series:	Acta Crystallographica Section E: Crystallographic Communications
Subjects:	crystal structure coordination complex titanium in trigonal–bipyramidal coordination
Online Access:	http://scripts.iucr.org/cgi-bin/paper?S2056989016020156

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spelling	doaj-71fd26cebf3e458893a02967c2358bc02020-11-25T00:10:50ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902017-01-01731889110.1107/S2056989016020156rz5202Crystal structure of a rare trigonal bipyramidal titanium(IV) coordination complex: trichlorido(3,3′-di-tert-butyl-2′-hydroxy-5,5′,6,6′-tetramethyl-1,1′-biphenyl-2-olato-κO2)(tetrahydrofuran-κO)titanium(IV)Yun Young Kim0Joseph M. Tanski1Department of Chemistry, Vassar College, Poughkeepsie, NY 12604, USADepartment of Chemistry, Vassar College, Poughkeepsie, NY 12604, USAThe title compound, [Ti(C24H33O2)Cl3(C4H8O)], is a rare example of a trigonal–bipyramidal titanium coordination complex with three chloride and two oxygen donor ligands. The asymmetric unit contains two independent molecules having essentially the same conformation. The molecules feature the titanium(IV) metal cation complexed with three chloride ligands, a tetrahydrofuran molecule, and one oxygen atom from the resolved ligand precursor (R)-(+)-5,5′,6,6′-tetramethyl-3,3′-di-t-butyl-1,1′-biphenyl-2,2′-diol, where the remaining phenolic hydrogen atom engages in intermolecular O—H...Cl hydrogen bonding. In one molecule, the THF ligand is disordered over two orientations with refined site occupancies of 0.50 (3).http://scripts.iucr.org/cgi-bin/paper?S2056989016020156crystal structurecoordination complextitanium in trigonal–bipyramidal coordination
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Yun Young Kim Joseph M. Tanski
spellingShingle	Yun Young Kim Joseph M. Tanski Crystal structure of a rare trigonal bipyramidal titanium(IV) coordination complex: trichlorido(3,3′-di-tert-butyl-2′-hydroxy-5,5′,6,6′-tetramethyl-1,1′-biphenyl-2-olato-κO2)(tetrahydrofuran-κO)titanium(IV) Acta Crystallographica Section E: Crystallographic Communications crystal structure coordination complex titanium in trigonal–bipyramidal coordination
author_facet	Yun Young Kim Joseph M. Tanski
author_sort	Yun Young Kim
title	Crystal structure of a rare trigonal bipyramidal titanium(IV) coordination complex: trichlorido(3,3′-di-tert-butyl-2′-hydroxy-5,5′,6,6′-tetramethyl-1,1′-biphenyl-2-olato-κO2)(tetrahydrofuran-κO)titanium(IV)
title_short	Crystal structure of a rare trigonal bipyramidal titanium(IV) coordination complex: trichlorido(3,3′-di-tert-butyl-2′-hydroxy-5,5′,6,6′-tetramethyl-1,1′-biphenyl-2-olato-κO2)(tetrahydrofuran-κO)titanium(IV)
title_full	Crystal structure of a rare trigonal bipyramidal titanium(IV) coordination complex: trichlorido(3,3′-di-tert-butyl-2′-hydroxy-5,5′,6,6′-tetramethyl-1,1′-biphenyl-2-olato-κO2)(tetrahydrofuran-κO)titanium(IV)
title_fullStr	Crystal structure of a rare trigonal bipyramidal titanium(IV) coordination complex: trichlorido(3,3′-di-tert-butyl-2′-hydroxy-5,5′,6,6′-tetramethyl-1,1′-biphenyl-2-olato-κO2)(tetrahydrofuran-κO)titanium(IV)
title_full_unstemmed	Crystal structure of a rare trigonal bipyramidal titanium(IV) coordination complex: trichlorido(3,3′-di-tert-butyl-2′-hydroxy-5,5′,6,6′-tetramethyl-1,1′-biphenyl-2-olato-κO2)(tetrahydrofuran-κO)titanium(IV)
title_sort	crystal structure of a rare trigonal bipyramidal titanium(iv) coordination complex: trichlorido(3,3′-di-tert-butyl-2′-hydroxy-5,5′,6,6′-tetramethyl-1,1′-biphenyl-2-olato-κo2)(tetrahydrofuran-κo)titanium(iv)
publisher	International Union of Crystallography
series	Acta Crystallographica Section E: Crystallographic Communications
issn	2056-9890
publishDate	2017-01-01
description	The title compound, [Ti(C24H33O2)Cl3(C4H8O)], is a rare example of a trigonal–bipyramidal titanium coordination complex with three chloride and two oxygen donor ligands. The asymmetric unit contains two independent molecules having essentially the same conformation. The molecules feature the titanium(IV) metal cation complexed with three chloride ligands, a tetrahydrofuran molecule, and one oxygen atom from the resolved ligand precursor (R)-(+)-5,5′,6,6′-tetramethyl-3,3′-di-t-butyl-1,1′-biphenyl-2,2′-diol, where the remaining phenolic hydrogen atom engages in intermolecular O—H...Cl hydrogen bonding. In one molecule, the THF ligand is disordered over two orientations with refined site occupancies of 0.50 (3).
topic	crystal structure coordination complex titanium in trigonal–bipyramidal coordination
url	http://scripts.iucr.org/cgi-bin/paper?S2056989016020156
work_keys_str_mv	AT yunyoungkim crystalstructureofararetrigonalbipyramidaltitaniumivcoordinationcomplextrichlorido33ditertbutyl2hydroxy5566tetramethyl11biphenyl2olatoko2tetrahydrofurankotitaniumiv AT josephmtanski crystalstructureofararetrigonalbipyramidaltitaniumivcoordinationcomplextrichlorido33ditertbutyl2hydroxy5566tetramethyl11biphenyl2olatoko2tetrahydrofurankotitaniumiv
_version_	1725406726871580672

Crystal structure of a rare trigonal bipyramidal titanium(IV) coordination complex: trichlorido(3,3′-di-tert-butyl-2′-hydroxy-5,5′,6,6′-tetramethyl-1,1′-biphenyl-2-olato-κO2)(tetrahydrofuran-κO)titanium(IV)

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