Citrate and Polyvinylpyrrolidone Stabilized Silver Nanoparticles as Selective Colorimetric Sensor for Aluminum (III) Ions in Real Water Samples

• Main Authors: Paula Ruíz del Portal-Vázquez, Germán López-Pérez, Rafael Prado-Gotor, Cristina Román-Hidalgo, María Jesús Martín-Valero
• Format: Article
• Language: English
• Published: MDPI AG 2020-03-01
• Series: Materials
• Subjects: silver nanoparticles; polyvinylpyrrolidone; surface plasmon band deconvolution; sensoring; aluminum
• Online Access: https://www.mdpi.com/1996-1944/13/6/1373

The use of silver nanoparticles stabilized with citrate and polyvinylpyrrolidone as a sensor for aluminum ions determination is proposed in this paper. These non-functionalized and specific nanoparticles provide a highly selective and sensitive detection system for aluminum in acidic solutions. The synthesized nanoparticles were characterized by transmission electron microscopy. Surface plasmon band deconvolution analysis was applied to study the interaction between silver nanoparticles and aluminum ions in solution. The interaction band in the UV-visible region was used as an analytical signal for quantitation purposes. The proposed detection system offers an effective AND wide linearity range (0.1−10³ nM), specificity for Al(III) in THE presence of other metallic ions in solution, as well as high sensitivity (limit of detection = 40.5 nM). The proposed silver-nanoparticles-based sensor WAS successfully used for detecting Al(III) in real water samples.