Evidence of nanodiamond-self-assembly in a liquid crystal, and the consequent impacts on the liquid crystal properties

A small quantity of nanodiamonds (NDs) was dispersed in a nematic liquid crystal (LC), and the NDs were found to exhibit an anisotropic self-assembly along the nematic director. The anisotropic assembly of the NDs in the LC matrix was probed by measuring the dielectric anisotropy, Δε, of the LC+ND s...

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Bibliographic Details
Main Authors: Rajratan Basu, Nicole Skaggs, Samuel Shalov, Peter Brereton
Format: Article
Language:English
Published: AIP Publishing LLC 2017-07-01
Series:AIP Advances
Online Access:http://dx.doi.org/10.1063/1.4993455
Description
Summary:A small quantity of nanodiamonds (NDs) was dispersed in a nematic liquid crystal (LC), and the NDs were found to exhibit an anisotropic self-assembly along the nematic director. The anisotropic assembly of the NDs in the LC matrix was probed by measuring the dielectric anisotropy, Δε, of the LC+ND system, which showed a significant increase in Δε. Additional studies revealed that the presence of NDs reduced the rotational viscosity and the pretilt angle of the LC. The studies were carried out with several ND concentrations in the LC and the experimental results coherently suggest that there exists an optimal concentration of ND. Above this optimal ND concentration, the anisotropic assembly of the NDs was found to be not effective anymore. The rotational viscosity and the pretilt angle of the LC were found to increase above the optimal concentration of ND.
ISSN:2158-3226