Poly[hexaaquabis(μ4-pyrimidine-4,6-dicarboxylato)tetralithium]

Poly[hexaaquabis(μ4-pyrimidine-4,6-dicarboxylato)tetralithium]

The asymmetric unit of the title compound, [Li4(C6H2N2O4)2(H2O)6]n, comprises two Li+ ions bridged by a completely deprotonated pyrimidine-3,6-dicarboxylate ligand and coordinated by two water molecules; the asymmetric units related by an inversion operation create a structural unit which forms part...

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Main Authors: Wojciech Starosta, Janusz Leciejewicz
Format: Article
Language:English
Published: International Union of Crystallography 2012-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812038755
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spelling doaj-702df7ca9383404c9f16814b7b6778ed2020-11-25T00:14:19ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-10-016810m1270m127110.1107/S1600536812038755Poly[hexaaquabis(μ4-pyrimidine-4,6-dicarboxylato)tetralithium]Wojciech StarostaJanusz LeciejewiczThe asymmetric unit of the title compound, [Li4(C6H2N2O4)2(H2O)6]n, comprises two Li+ ions bridged by a completely deprotonated pyrimidine-3,6-dicarboxylate ligand and coordinated by two water molecules; the asymmetric units related by an inversion operation create a structural unit which forms part of a two-dimensional polymeric structure parallel to (10-1). One of the Li+ ions shows a distorted tetrahedral arrangement involving two symmetry-related coordinating water molecules and two carboxylate O atoms. The other Li+ ion is in distorted trigonal–bipyramidal geometry defined by N and O atoms of the ligands and a water molecule. Water O atoms are proton donors to carboxylate O atoms forming hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536812038755
collection DOAJ
language English
format Article
sources DOAJ
author Wojciech Starosta
Janusz Leciejewicz
spellingShingle Wojciech Starosta
Janusz Leciejewicz
Poly[hexaaquabis(μ4-pyrimidine-4,6-dicarboxylato)tetralithium]
Acta Crystallographica Section E
author_facet Wojciech Starosta
Janusz Leciejewicz
author_sort Wojciech Starosta
title Poly[hexaaquabis(μ4-pyrimidine-4,6-dicarboxylato)tetralithium]
title_short Poly[hexaaquabis(μ4-pyrimidine-4,6-dicarboxylato)tetralithium]
title_full Poly[hexaaquabis(μ4-pyrimidine-4,6-dicarboxylato)tetralithium]
title_fullStr Poly[hexaaquabis(μ4-pyrimidine-4,6-dicarboxylato)tetralithium]
title_full_unstemmed Poly[hexaaquabis(μ4-pyrimidine-4,6-dicarboxylato)tetralithium]
title_sort poly[hexaaquabis(μ4-pyrimidine-4,6-dicarboxylato)tetralithium]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-10-01
description The asymmetric unit of the title compound, [Li4(C6H2N2O4)2(H2O)6]n, comprises two Li+ ions bridged by a completely deprotonated pyrimidine-3,6-dicarboxylate ligand and coordinated by two water molecules; the asymmetric units related by an inversion operation create a structural unit which forms part of a two-dimensional polymeric structure parallel to (10-1). One of the Li+ ions shows a distorted tetrahedral arrangement involving two symmetry-related coordinating water molecules and two carboxylate O atoms. The other Li+ ion is in distorted trigonal–bipyramidal geometry defined by N and O atoms of the ligands and a water molecule. Water O atoms are proton donors to carboxylate O atoms forming hydrogen bonds.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812038755
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AT januszleciejewicz polyhexaaquabisamp9564pyrimidine46dicarboxylatotetralithium
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