Bis{μ-2-(1H-indol-3-yl)-N′-[1-(5-methyl-2-oxidophenyl)ethylidene]acetohydrazidato}bis[aquazinc(II)] dimethyl sulfoxide tetrasolvate

Bis{μ-2-(1H-indol-3-yl)-N′-[1-(5-methyl-2-oxidophenyl)ethylidene]acetohydrazidato}bis[aquazinc(II)] dimethyl sulfoxide tetrasolvate

The dinuclear title compound, [Zn2(C19H17N3O2)2(H2O)2]·4C2H6OS, lies about a center of inversion. The deprotonated monoanion O,N,O-chelates the Zn atom; the hydroxy O atom also engages in bonding to the symmetry-related Zn atom so that one N and three O atoms form a square around the metal....

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Main Authors: Hapipah M. Ali, Subramaniam Puvaneswary, Ward T. Robinson, Seik Weng Ng, Kadir Zuraini
Format: Article
Language:English
Published: International Union of Crystallography 2008-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808022034
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spelling doaj-6fe18def4cf74d74ae15a1be34bdccaf2020-11-24T20:47:11ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-08-01648m1047m104710.1107/S1600536808022034Bis{μ-2-(1H-indol-3-yl)-N′-[1-(5-methyl-2-oxidophenyl)ethylidene]acetohydrazidato}bis[aquazinc(II)] dimethyl sulfoxide tetrasolvateHapipah M. AliSubramaniam PuvaneswaryWard T. RobinsonSeik Weng NgKadir ZurainiThe dinuclear title compound, [Zn2(C19H17N3O2)2(H2O)2]·4C2H6OS, lies about a center of inversion. The deprotonated monoanion O,N,O-chelates the Zn atom; the hydroxy O atom also engages in bonding to the symmetry-related Zn atom so that one N and three O atoms form a square around the metal. The coordination geometry is square-pyramidal, with the apical site occupied by a water molecule. Hydrogen bonds, with the water molecule serving as donor atom, lead to the formation of a linear chain motif. There is an N—H...O hydrogen bond between the complex molecule and solvent O atom.http://scripts.iucr.org/cgi-bin/paper?S1600536808022034
collection DOAJ
language English
format Article
sources DOAJ
author Hapipah M. Ali
Subramaniam Puvaneswary
Ward T. Robinson
Seik Weng Ng
Kadir Zuraini
spellingShingle Hapipah M. Ali
Subramaniam Puvaneswary
Ward T. Robinson
Seik Weng Ng
Kadir Zuraini
Bis{μ-2-(1H-indol-3-yl)-N′-[1-(5-methyl-2-oxidophenyl)ethylidene]acetohydrazidato}bis[aquazinc(II)] dimethyl sulfoxide tetrasolvate
Acta Crystallographica Section E
author_facet Hapipah M. Ali
Subramaniam Puvaneswary
Ward T. Robinson
Seik Weng Ng
Kadir Zuraini
author_sort Hapipah M. Ali
title Bis{μ-2-(1H-indol-3-yl)-N′-[1-(5-methyl-2-oxidophenyl)ethylidene]acetohydrazidato}bis[aquazinc(II)] dimethyl sulfoxide tetrasolvate
title_short Bis{μ-2-(1H-indol-3-yl)-N′-[1-(5-methyl-2-oxidophenyl)ethylidene]acetohydrazidato}bis[aquazinc(II)] dimethyl sulfoxide tetrasolvate
title_full Bis{μ-2-(1H-indol-3-yl)-N′-[1-(5-methyl-2-oxidophenyl)ethylidene]acetohydrazidato}bis[aquazinc(II)] dimethyl sulfoxide tetrasolvate
title_fullStr Bis{μ-2-(1H-indol-3-yl)-N′-[1-(5-methyl-2-oxidophenyl)ethylidene]acetohydrazidato}bis[aquazinc(II)] dimethyl sulfoxide tetrasolvate
title_full_unstemmed Bis{μ-2-(1H-indol-3-yl)-N′-[1-(5-methyl-2-oxidophenyl)ethylidene]acetohydrazidato}bis[aquazinc(II)] dimethyl sulfoxide tetrasolvate
title_sort bis{μ-2-(1h-indol-3-yl)-n′-[1-(5-methyl-2-oxidophenyl)ethylidene]acetohydrazidato}bis[aquazinc(ii)] dimethyl sulfoxide tetrasolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-08-01
description The dinuclear title compound, [Zn2(C19H17N3O2)2(H2O)2]·4C2H6OS, lies about a center of inversion. The deprotonated monoanion O,N,O-chelates the Zn atom; the hydroxy O atom also engages in bonding to the symmetry-related Zn atom so that one N and three O atoms form a square around the metal. The coordination geometry is square-pyramidal, with the apical site occupied by a water molecule. Hydrogen bonds, with the water molecule serving as donor atom, lead to the formation of a linear chain motif. There is an N—H...O hydrogen bond between the complex molecule and solvent O atom.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808022034
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AT subramaniampuvaneswary bis95621hindol3yln824215methyl2oxidophenylethylideneacetohydrazidatobisaquazinciidimethylsulfoxidetetrasolvate
AT wardtrobinson bis95621hindol3yln824215methyl2oxidophenylethylideneacetohydrazidatobisaquazinciidimethylsulfoxidetetrasolvate
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