The electrochemistry of carbon steel in simulated concrete pore water in boom clay repository environments
The prediction of corrosion damage of canisters to experimentally inaccessible times is vitally important in assessing various concepts for the disposal of High Level Nuclear Waste. Such prediction can only be made using deterministic models, whose predictions are constrained by the time-invariant n...
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| Format: | Article |
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EDP Sciences
2011-04-01
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| Series: | EPJ Web of Conferences |
| Online Access: | http://dx.doi.org/10.1051/epjconf/20111204003 |
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doaj-6f58dc0f4fbe44258295c18fc9a4a54d2021-08-02T17:24:23ZengEDP SciencesEPJ Web of Conferences2100-014X2011-04-01120400310.1051/epjconf/20111204003The electrochemistry of carbon steel in simulated concrete pore water in boom clay repository environmentsRosas-Camacho O.Azizi O.Lee S.K.Saleh A.Macdonald D.D.Al-Marzooqi A.Taylor M.The prediction of corrosion damage of canisters to experimentally inaccessible times is vitally important in assessing various concepts for the disposal of High Level Nuclear Waste. Such prediction can only be made using deterministic models, whose predictions are constrained by the time-invariant natural laws. In this paper, we describe the measurement of experimental electrochemical data that will allow the prediction of damage to the carbon steel overpack of the super container in Belgium’s proposed Boom Clay repository by using the Point Defect Model (PDM). PDM parameter values are obtained by optimizing the model on experimental, wide-band electrochemical impedance spectroscopy data. http://dx.doi.org/10.1051/epjconf/20111204003 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Rosas-Camacho O. Azizi O. Lee S.K. Saleh A. Macdonald D.D. Al-Marzooqi A. Taylor M. |
| spellingShingle |
Rosas-Camacho O. Azizi O. Lee S.K. Saleh A. Macdonald D.D. Al-Marzooqi A. Taylor M. The electrochemistry of carbon steel in simulated concrete pore water in boom clay repository environments EPJ Web of Conferences |
| author_facet |
Rosas-Camacho O. Azizi O. Lee S.K. Saleh A. Macdonald D.D. Al-Marzooqi A. Taylor M. |
| author_sort |
Rosas-Camacho O. |
| title |
The electrochemistry of carbon steel in simulated concrete pore water in boom clay repository environments |
| title_short |
The electrochemistry of carbon steel in simulated concrete pore water in boom clay repository environments |
| title_full |
The electrochemistry of carbon steel in simulated concrete pore water in boom clay repository environments |
| title_fullStr |
The electrochemistry of carbon steel in simulated concrete pore water in boom clay repository environments |
| title_full_unstemmed |
The electrochemistry of carbon steel in simulated concrete pore water in boom clay repository environments |
| title_sort |
electrochemistry of carbon steel in simulated concrete pore water in boom clay repository environments |
| publisher |
EDP Sciences |
| series |
EPJ Web of Conferences |
| issn |
2100-014X |
| publishDate |
2011-04-01 |
| description |
The prediction of corrosion damage of canisters to experimentally inaccessible times is vitally important in assessing various concepts for the disposal of High Level Nuclear Waste. Such prediction can only be made using deterministic models, whose predictions are constrained by the time-invariant natural laws. In this paper, we describe the measurement of experimental electrochemical data that will allow the prediction of damage to the carbon steel overpack of the super container in Belgium’s proposed Boom Clay repository by using the Point Defect Model (PDM). PDM parameter values are obtained by optimizing the model on experimental, wide-band electrochemical impedance spectroscopy data. |
| url |
http://dx.doi.org/10.1051/epjconf/20111204003 |
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