catena-Poly[(chloridozinc)-μ-5-(1-methyl-1H-benzimidazol-2-yl-κN3)-1,2,3-triazol-1-ido-κ2N1:N3]

catena-Poly[(chloridozinc)-μ-5-(1-methyl-1H-benzimidazol-2-yl-κN3)-1,2,3-triazol-1-ido-κ2N1:N3]

In the title complex, [Zn(C10H8N5)Cl]n, the ZnII ion is four-coordinated by one Cl atom and three N atoms from two in situ-generated deprotonated 5-(1-methyl-1H-benzimidazol-2-yl-κN3)-1,2,3-triazol-1-ide ligands in a slightly distorted tetrahedral geometry. The ZnII ions are bridged by...

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Main Authors: Chen-Guang Sun, Ji-Rong Song
Format: Article
Language:English
Published: International Union of Crystallography 2012-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812012706
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spelling doaj-6f0a5c9dd642431d85a2dacece99c4802020-11-25T00:31:14ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-04-01684m520m52010.1107/S1600536812012706catena-Poly[(chloridozinc)-μ-5-(1-methyl-1H-benzimidazol-2-yl-κN3)-1,2,3-triazol-1-ido-κ2N1:N3]Chen-Guang SunJi-Rong SongIn the title complex, [Zn(C10H8N5)Cl]n, the ZnII ion is four-coordinated by one Cl atom and three N atoms from two in situ-generated deprotonated 5-(1-methyl-1H-benzimidazol-2-yl-κN3)-1,2,3-triazol-1-ide ligands in a slightly distorted tetrahedral geometry. The ZnII ions are bridged by the ligands, forming a helical chain along [001]. C—H...N and C—H...Cl hydrogen bonds and π–π interactions between the imidazole rings [centroid–centroid distance = 3.4244 (10) Å] assemble the chains into a three-dimensional supramolecular network.http://scripts.iucr.org/cgi-bin/paper?S1600536812012706
collection DOAJ
language English
format Article
sources DOAJ
author Chen-Guang Sun
Ji-Rong Song
spellingShingle Chen-Guang Sun
Ji-Rong Song
catena-Poly[(chloridozinc)-μ-5-(1-methyl-1H-benzimidazol-2-yl-κN3)-1,2,3-triazol-1-ido-κ2N1:N3]
Acta Crystallographica Section E
author_facet Chen-Guang Sun
Ji-Rong Song
author_sort Chen-Guang Sun
title catena-Poly[(chloridozinc)-μ-5-(1-methyl-1H-benzimidazol-2-yl-κN3)-1,2,3-triazol-1-ido-κ2N1:N3]
title_short catena-Poly[(chloridozinc)-μ-5-(1-methyl-1H-benzimidazol-2-yl-κN3)-1,2,3-triazol-1-ido-κ2N1:N3]
title_full catena-Poly[(chloridozinc)-μ-5-(1-methyl-1H-benzimidazol-2-yl-κN3)-1,2,3-triazol-1-ido-κ2N1:N3]
title_fullStr catena-Poly[(chloridozinc)-μ-5-(1-methyl-1H-benzimidazol-2-yl-κN3)-1,2,3-triazol-1-ido-κ2N1:N3]
title_full_unstemmed catena-Poly[(chloridozinc)-μ-5-(1-methyl-1H-benzimidazol-2-yl-κN3)-1,2,3-triazol-1-ido-κ2N1:N3]
title_sort catena-poly[(chloridozinc)-μ-5-(1-methyl-1h-benzimidazol-2-yl-κn3)-1,2,3-triazol-1-ido-κ2n1:n3]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-04-01
description In the title complex, [Zn(C10H8N5)Cl]n, the ZnII ion is four-coordinated by one Cl atom and three N atoms from two in situ-generated deprotonated 5-(1-methyl-1H-benzimidazol-2-yl-κN3)-1,2,3-triazol-1-ide ligands in a slightly distorted tetrahedral geometry. The ZnII ions are bridged by the ligands, forming a helical chain along [001]. C—H...N and C—H...Cl hydrogen bonds and π–π interactions between the imidazole rings [centroid–centroid distance = 3.4244 (10) Å] assemble the chains into a three-dimensional supramolecular network.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812012706
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AT jirongsong catenapolychloridozincamp95651methyl1hbenzimidazol2ylamp954n3123triazol1idoamp9542n1n3
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