Bis[1,3-bis(benzimidazol-2-yl)-2-oxapropane]cobalt(II) dipicrate acetonitrile trisolvate

Bis[1,3-bis(benzimidazol-2-yl)-2-oxapropane]cobalt(II) dipicrate acetonitrile trisolvate

In the title compound, [Co(C16H14N4O)2](C6H2N3O7)2·3CH3CN, the CoII ion is located on a crystallographic twofold rotation axis and is coordinated in a slightly distorted tetrahedral environment by four N atoms from the two bidentate N-heterocycles. The crystal structure is stabilized by...

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Bibliographic Details
Main Authors: Baoliang Qi, Qingyu Sun, Ruirui Yun, Xingcai Huang, Huilu Wu
Format: Article
Language:English
Published: International Union of Crystallography 2009-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809024234
Description
Summary:In the title compound, [Co(C16H14N4O)2](C6H2N3O7)2·3CH3CN, the CoII ion is located on a crystallographic twofold rotation axis and is coordinated in a slightly distorted tetrahedral environment by four N atoms from the two bidentate N-heterocycles. The crystal structure is stabilized by intermolecular N—H...O and N—H...N hydrogen bonds. One of the acetonitrile solvent molecules also lies on a twofold rotation axis.
ISSN:1600-5368

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