Effects of Sulfurization Pressure on the Conversion Efficiency of Cosputtered Cu2ZnSnS4 Thin Film Solar Cells

We report herein Cu2ZnSnS4 (CZTS) thin film solar cells with 6.75% conversion efficiency, without an antireflection coating. The CZTS precursors have been prepared by cosputtering using three different targets on Mo-coated substrates: copper (Cu), tin sulfide (SnS), and zinc (Zn). The postsulfurizat...

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Main Authors: Arun Khalkar, Kwang-Soo Lim, Seong-Man Yu, Dong-Wook Shin, Tae-Sik Oh, Ji-Beom Yoo
Format: Article
Language:English
Published: Hindawi Limited 2015-01-01
Series:International Journal of Photoenergy
Online Access:http://dx.doi.org/10.1155/2015/750846
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spelling doaj-6d61f3f8fe694848ac4972abb08bc83d2020-11-24T20:56:51ZengHindawi LimitedInternational Journal of Photoenergy1110-662X1687-529X2015-01-01201510.1155/2015/750846750846Effects of Sulfurization Pressure on the Conversion Efficiency of Cosputtered Cu2ZnSnS4 Thin Film Solar CellsArun Khalkar0Kwang-Soo Lim1Seong-Man Yu2Dong-Wook Shin3Tae-Sik Oh4Ji-Beom Yoo5SKKU Advanced Institute of Nanotechnology (SAINT), Sungkyunkwan University, Suwon 440746, Republic of KoreaSKKU Advanced Institute of Nanotechnology (SAINT), Sungkyunkwan University, Suwon 440746, Republic of KoreaSKKU Advanced Institute of Nanotechnology (SAINT), Sungkyunkwan University, Suwon 440746, Republic of KoreaSKKU Advanced Institute of Nanotechnology (SAINT), Sungkyunkwan University, Suwon 440746, Republic of KoreaDepartment of Information Display, Sun Moon University, Asan 336708, Republic of KoreaSKKU Advanced Institute of Nanotechnology (SAINT), Sungkyunkwan University, Suwon 440746, Republic of KoreaWe report herein Cu2ZnSnS4 (CZTS) thin film solar cells with 6.75% conversion efficiency, without an antireflection coating. The CZTS precursors have been prepared by cosputtering using three different targets on Mo-coated substrates: copper (Cu), tin sulfide (SnS), and zinc (Zn). The postsulfurization was carried out at different pressures in a H2S/N2 environment at 550°C for one hour. A comparative study on the performances of solar cells with CZTS absorber layers prepared at different sulfurization pressures was carried out. The device efficiency of 1.67% using CZTS absorber and low pressure sulfurization is drastically improved, to an efficiency of 6.75% with atmospheric pressure sulfurization.http://dx.doi.org/10.1155/2015/750846
collection DOAJ
language English
format Article
sources DOAJ
author Arun Khalkar
Kwang-Soo Lim
Seong-Man Yu
Dong-Wook Shin
Tae-Sik Oh
Ji-Beom Yoo
spellingShingle Arun Khalkar
Kwang-Soo Lim
Seong-Man Yu
Dong-Wook Shin
Tae-Sik Oh
Ji-Beom Yoo
Effects of Sulfurization Pressure on the Conversion Efficiency of Cosputtered Cu2ZnSnS4 Thin Film Solar Cells
International Journal of Photoenergy
author_facet Arun Khalkar
Kwang-Soo Lim
Seong-Man Yu
Dong-Wook Shin
Tae-Sik Oh
Ji-Beom Yoo
author_sort Arun Khalkar
title Effects of Sulfurization Pressure on the Conversion Efficiency of Cosputtered Cu2ZnSnS4 Thin Film Solar Cells
title_short Effects of Sulfurization Pressure on the Conversion Efficiency of Cosputtered Cu2ZnSnS4 Thin Film Solar Cells
title_full Effects of Sulfurization Pressure on the Conversion Efficiency of Cosputtered Cu2ZnSnS4 Thin Film Solar Cells
title_fullStr Effects of Sulfurization Pressure on the Conversion Efficiency of Cosputtered Cu2ZnSnS4 Thin Film Solar Cells
title_full_unstemmed Effects of Sulfurization Pressure on the Conversion Efficiency of Cosputtered Cu2ZnSnS4 Thin Film Solar Cells
title_sort effects of sulfurization pressure on the conversion efficiency of cosputtered cu2znsns4 thin film solar cells
publisher Hindawi Limited
series International Journal of Photoenergy
issn 1110-662X
1687-529X
publishDate 2015-01-01
description We report herein Cu2ZnSnS4 (CZTS) thin film solar cells with 6.75% conversion efficiency, without an antireflection coating. The CZTS precursors have been prepared by cosputtering using three different targets on Mo-coated substrates: copper (Cu), tin sulfide (SnS), and zinc (Zn). The postsulfurization was carried out at different pressures in a H2S/N2 environment at 550°C for one hour. A comparative study on the performances of solar cells with CZTS absorber layers prepared at different sulfurization pressures was carried out. The device efficiency of 1.67% using CZTS absorber and low pressure sulfurization is drastically improved, to an efficiency of 6.75% with atmospheric pressure sulfurization.
url http://dx.doi.org/10.1155/2015/750846
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