Application of “Boomerang” Linear Polystyrene-Stabilized Pd Nanoparticles to a Series of C-C Coupling Reactions in Water

Application of “Boomerang” Linear Polystyrene-Stabilized Pd Nanoparticles to a Series of C-C Coupling Reactions in Water

The application of a catch-and-release system for soluble Pd species between water (reaction medium) and polystyrene (polymer support) was examined in the Suzuki coupling reaction with 2-bromothiophene and the Heck reaction with styrene or bromobenzene. Although a slight increase in particle size wa...

Full description

Bibliographic Details
Main Authors: Atsushi Ohtaka, Toshiyuki Okagaki, Go Hamasaka, Yasuhiro Uozumi, Tsutomu Shinagawa, Osamu Shimomura, Ryôki Nomura
Format: Article
Language:English
Published: MDPI AG 2015-02-01
Series:Catalysts
Subjects:
nanoparticles
boomerang catalyst
C-C coupling
water
Online Access:http://www.mdpi.com/2073-4344/5/1/106
id doaj-6d553e4564ff4b7b81f260e56903210b
record_format Article
spelling doaj-6d553e4564ff4b7b81f260e56903210b2020-11-25T00:49:09ZengMDPI AGCatalysts2073-43442015-02-015110611810.3390/catal5010106catal5010106Application of “Boomerang” Linear Polystyrene-Stabilized Pd Nanoparticles to a Series of C-C Coupling Reactions in WaterAtsushi Ohtaka0Toshiyuki Okagaki1Go Hamasaka2Yasuhiro Uozumi3Tsutomu Shinagawa4Osamu Shimomura5Ryôki Nomura6Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology, 5-16-1 Ohmiya, Asahi, Osaka 535-8585, JapanDepartment of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology, 5-16-1 Ohmiya, Asahi, Osaka 535-8585, JapanInstitute for Molecular Science (IMS), Higashiyama 5-1, Myodaiji, Okazaki 444-8787, JapanInstitute for Molecular Science (IMS), Higashiyama 5-1, Myodaiji, Okazaki 444-8787, JapanOsaka Municipal Technical Research Institute, 1-6-50 Morinomiya, Joto, Osaka, 536-8553, JapanDepartment of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology, 5-16-1 Ohmiya, Asahi, Osaka 535-8585, JapanDepartment of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology, 5-16-1 Ohmiya, Asahi, Osaka 535-8585, JapanThe application of a catch-and-release system for soluble Pd species between water (reaction medium) and polystyrene (polymer support) was examined in the Suzuki coupling reaction with 2-bromothiophene and the Heck reaction with styrene or bromobenzene. Although a slight increase in particle size was observed by TEM after re-stabilization of the Pd species on linear polystyrene, no agglomeration was observed.http://www.mdpi.com/2073-4344/5/1/106nanoparticlesboomerang catalystC-C couplingwater
collection DOAJ
language English
format Article
sources DOAJ
author Atsushi Ohtaka
Toshiyuki Okagaki
Go Hamasaka
Yasuhiro Uozumi
Tsutomu Shinagawa
Osamu Shimomura
Ryôki Nomura
spellingShingle Atsushi Ohtaka
Toshiyuki Okagaki
Go Hamasaka
Yasuhiro Uozumi
Tsutomu Shinagawa
Osamu Shimomura
Ryôki Nomura
Application of “Boomerang” Linear Polystyrene-Stabilized Pd Nanoparticles to a Series of C-C Coupling Reactions in Water
Catalysts
nanoparticles
boomerang catalyst
C-C coupling
water
author_facet Atsushi Ohtaka
Toshiyuki Okagaki
Go Hamasaka
Yasuhiro Uozumi
Tsutomu Shinagawa
Osamu Shimomura
Ryôki Nomura
author_sort Atsushi Ohtaka
title Application of “Boomerang” Linear Polystyrene-Stabilized Pd Nanoparticles to a Series of C-C Coupling Reactions in Water
title_short Application of “Boomerang” Linear Polystyrene-Stabilized Pd Nanoparticles to a Series of C-C Coupling Reactions in Water
title_full Application of “Boomerang” Linear Polystyrene-Stabilized Pd Nanoparticles to a Series of C-C Coupling Reactions in Water
title_fullStr Application of “Boomerang” Linear Polystyrene-Stabilized Pd Nanoparticles to a Series of C-C Coupling Reactions in Water
title_full_unstemmed Application of “Boomerang” Linear Polystyrene-Stabilized Pd Nanoparticles to a Series of C-C Coupling Reactions in Water
title_sort application of “boomerang” linear polystyrene-stabilized pd nanoparticles to a series of c-c coupling reactions in water
publisher MDPI AG
series Catalysts
issn 2073-4344
publishDate 2015-02-01
description The application of a catch-and-release system for soluble Pd species between water (reaction medium) and polystyrene (polymer support) was examined in the Suzuki coupling reaction with 2-bromothiophene and the Heck reaction with styrene or bromobenzene. Although a slight increase in particle size was observed by TEM after re-stabilization of the Pd species on linear polystyrene, no agglomeration was observed.
topic nanoparticles
boomerang catalyst
C-C coupling
water
url http://www.mdpi.com/2073-4344/5/1/106
work_keys_str_mv AT atsushiohtaka applicationofboomeranglinearpolystyrenestabilizedpdnanoparticlestoaseriesofcccouplingreactionsinwater
AT toshiyukiokagaki applicationofboomeranglinearpolystyrenestabilizedpdnanoparticlestoaseriesofcccouplingreactionsinwater
AT gohamasaka applicationofboomeranglinearpolystyrenestabilizedpdnanoparticlestoaseriesofcccouplingreactionsinwater
AT yasuhirouozumi applicationofboomeranglinearpolystyrenestabilizedpdnanoparticlestoaseriesofcccouplingreactionsinwater
AT tsutomushinagawa applicationofboomeranglinearpolystyrenestabilizedpdnanoparticlestoaseriesofcccouplingreactionsinwater
AT osamushimomura applicationofboomeranglinearpolystyrenestabilizedpdnanoparticlestoaseriesofcccouplingreactionsinwater
AT ryokinomura applicationofboomeranglinearpolystyrenestabilizedpdnanoparticlestoaseriesofcccouplingreactionsinwater
_version_ 1725252636668592128

Similar Items