Building complex carbon skeletons with ethynyl[2.2]paracyclophanes

Building complex carbon skeletons with ethynyl[2.2]paracyclophanes

Ethynyl[2.2]paracyclophanes are shown to be useful substrates for the preparation of complex, highly unsaturated carbon frameworks. Thus both the pseudo-geminal- 2 and the pseudo-ortho-diethynylcyclophane 4 can be dimerized by Glaser coupling to the respective dimers 9/10 and 11/12. Whereas the form...

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Bibliographic Details
Main Authors: Ina Dix, Lidija Bondarenko, Peter G. Jones, Thomas Oeser, Henning Hopf
Format: Article
Language:English
Published: Beilstein-Institut 2014-08-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
carbon-rich molecules
complex carbon scaffolds
cyclophanes
Glaser coupling
multibridged cyclophanes
X-ray analysis
Online Access:https://doi.org/10.3762/bjoc.10.209

Internet

https://doi.org/10.3762/bjoc.10.209

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