Quantum mechanic tunneling and efficiency of Faraday current-generating process in porous nanostructures

Thermodynamics and kinetics of lithium intercalation into C-SiO<sub>2</sub> nanocomposites are investigated. Dependencies of both differential capacity and intercalation kinetics on the nanocomposite size are established. The processes are analyzed in terms of the impedance model. The ob...

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Main Authors:	I.I. Grygorchak, B.A. Lukiyanets, D.V. Matulka
Format:	Article
Language:	English
Published:	Institute for Condensed Matter Physics 2011-06-01
Series:	Condensed Matter Physics
Subjects:	nanoobject electron state tunneling intercalation
Online Access:	http://dx.doi.org/10.5488/CMP.14.23705

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record_format	Article
spelling	doaj-6cd1870a744f48cb983c021911ede44d2020-11-24T23:54:42ZengInstitute for Condensed Matter PhysicsCondensed Matter Physics1607-324X2011-06-0114223705Quantum mechanic tunneling and efficiency of Faraday current-generating process in porous nanostructuresI.I. GrygorchakB.A. LukiyanetsD.V. MatulkaThermodynamics and kinetics of lithium intercalation into C-SiO<sub>2</sub> nanocomposites are investigated. Dependencies of both differential capacity and intercalation kinetics on the nanocomposite size are established. The processes are analyzed in terms of the impedance model. The obtained results are explained based on the quantum effect of interference blockade of electron tunneling into a nonmetallic nanoparticle. Propositions for the new electrochemical energy storage technology are presented.http://dx.doi.org/10.5488/CMP.14.23705 nanoobjectelectron statetunnelingintercalation
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	I.I. Grygorchak B.A. Lukiyanets D.V. Matulka
spellingShingle	I.I. Grygorchak B.A. Lukiyanets D.V. Matulka Quantum mechanic tunneling and efficiency of Faraday current-generating process in porous nanostructures Condensed Matter Physics nanoobject electron state tunneling intercalation
author_facet	I.I. Grygorchak B.A. Lukiyanets D.V. Matulka
author_sort	I.I. Grygorchak
title	Quantum mechanic tunneling and efficiency of Faraday current-generating process in porous nanostructures
title_short	Quantum mechanic tunneling and efficiency of Faraday current-generating process in porous nanostructures
title_full	Quantum mechanic tunneling and efficiency of Faraday current-generating process in porous nanostructures
title_fullStr	Quantum mechanic tunneling and efficiency of Faraday current-generating process in porous nanostructures
title_full_unstemmed	Quantum mechanic tunneling and efficiency of Faraday current-generating process in porous nanostructures
title_sort	quantum mechanic tunneling and efficiency of faraday current-generating process in porous nanostructures
publisher	Institute for Condensed Matter Physics
series	Condensed Matter Physics
issn	1607-324X
publishDate	2011-06-01
description	Thermodynamics and kinetics of lithium intercalation into C-SiO<sub>2</sub> nanocomposites are investigated. Dependencies of both differential capacity and intercalation kinetics on the nanocomposite size are established. The processes are analyzed in terms of the impedance model. The obtained results are explained based on the quantum effect of interference blockade of electron tunneling into a nonmetallic nanoparticle. Propositions for the new electrochemical energy storage technology are presented.
topic	nanoobject electron state tunneling intercalation
url	http://dx.doi.org/10.5488/CMP.14.23705
work_keys_str_mv	AT iigrygorchak quantummechanictunnelingandefficiencyoffaradaycurrentgeneratingprocessinporousnanostructures AT balukiyanets quantummechanictunnelingandefficiencyoffaradaycurrentgeneratingprocessinporousnanostructures AT dvmatulka quantummechanictunnelingandefficiencyoffaradaycurrentgeneratingprocessinporousnanostructures
_version_	1725465146400178176

Quantum mechanic tunneling and efficiency of Faraday current-generating process in porous nanostructures

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