N-(2-Acetamido-2-deoxy-β-d-glucopyranosyl)-N-(3-azidopropyl)-O-methylhydroxylamine

N-(2-Acetamido-2-deoxy-β-d-glucopyranosyl)-N-(3-azidopropyl)-O-methylhydroxylamine

The structure of the title compound, C12H23N5O6, solved using adequate data from a thin crystal plate, confirmed that this useful glycoconjugate was obtained in the ring-closed β-pyranose configuration with 4C1 conformation. The molecules are bound by O—H...O(OH) hydrogen bonds, notably in a zigzag...

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Main Authors: Stefan Munneke, Bridget L. Stocker, Mattie S. M. Timmer, Graeme J. Gainsford
Format: Article
Language:English
Published: International Union of Crystallography 2016-03-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
oxyamine glycoside
carbohydrate
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989016002164
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spelling doaj-6ccdfb64fee849e78e9fba158f1843e22020-11-24T20:54:17ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902016-03-0172334034210.1107/S2056989016002164lh5798N-(2-Acetamido-2-deoxy-β-d-glucopyranosyl)-N-(3-azidopropyl)-O-methylhydroxylamineStefan Munneke0Bridget L. Stocker1Mattie S. M. Timmer2Graeme J. Gainsford3School of Chemical and Physical Sciences, Victoria University of Wellington, PO Box 600, Wellington, New ZealandSchool of Chemical and Physical Sciences, Victoria University of Wellington, PO Box 600, Wellington, New ZealandSchool of Chemical and Physical Sciences, Victoria University of Wellington, PO Box 600, Wellington, New ZealandCallaghan Innovation, PO Box 31-310, Lower Hutt 5040, New ZealandThe structure of the title compound, C12H23N5O6, solved using adequate data from a thin crystal plate, confirmed that this useful glycoconjugate was obtained in the ring-closed β-pyranose configuration with 4C1 conformation. The molecules are bound by O—H...O(OH) hydrogen bonds, notably in a zigzag C(2) chain along the short b (screw) axis, supplemented with an R22(12) O—H...O(carbonyl) link along the a axis and other C(2) links. The absolute configuration was not unambiguously determined but was known from the synthetic chemistry, which used natural 2-acetamido-2-deoxy-d-glucose as the starting material.http://scripts.iucr.org/cgi-bin/paper?S2056989016002164crystal structureoxyamine glycosidecarbohydrate
collection DOAJ
language English
format Article
sources DOAJ
author Stefan Munneke
Bridget L. Stocker
Mattie S. M. Timmer
Graeme J. Gainsford
spellingShingle Stefan Munneke
Bridget L. Stocker
Mattie S. M. Timmer
Graeme J. Gainsford
N-(2-Acetamido-2-deoxy-β-d-glucopyranosyl)-N-(3-azidopropyl)-O-methylhydroxylamine
Acta Crystallographica Section E: Crystallographic Communications
crystal structure
oxyamine glycoside
carbohydrate
author_facet Stefan Munneke
Bridget L. Stocker
Mattie S. M. Timmer
Graeme J. Gainsford
author_sort Stefan Munneke
title N-(2-Acetamido-2-deoxy-β-d-glucopyranosyl)-N-(3-azidopropyl)-O-methylhydroxylamine
title_short N-(2-Acetamido-2-deoxy-β-d-glucopyranosyl)-N-(3-azidopropyl)-O-methylhydroxylamine
title_full N-(2-Acetamido-2-deoxy-β-d-glucopyranosyl)-N-(3-azidopropyl)-O-methylhydroxylamine
title_fullStr N-(2-Acetamido-2-deoxy-β-d-glucopyranosyl)-N-(3-azidopropyl)-O-methylhydroxylamine
title_full_unstemmed N-(2-Acetamido-2-deoxy-β-d-glucopyranosyl)-N-(3-azidopropyl)-O-methylhydroxylamine
title_sort n-(2-acetamido-2-deoxy-β-d-glucopyranosyl)-n-(3-azidopropyl)-o-methylhydroxylamine
publisher International Union of Crystallography
series Acta Crystallographica Section E: Crystallographic Communications
issn 2056-9890
publishDate 2016-03-01
description The structure of the title compound, C12H23N5O6, solved using adequate data from a thin crystal plate, confirmed that this useful glycoconjugate was obtained in the ring-closed β-pyranose configuration with 4C1 conformation. The molecules are bound by O—H...O(OH) hydrogen bonds, notably in a zigzag C(2) chain along the short b (screw) axis, supplemented with an R22(12) O—H...O(carbonyl) link along the a axis and other C(2) links. The absolute configuration was not unambiguously determined but was known from the synthetic chemistry, which used natural 2-acetamido-2-deoxy-d-glucose as the starting material.
topic crystal structure
oxyamine glycoside
carbohydrate
url http://scripts.iucr.org/cgi-bin/paper?S2056989016002164
work_keys_str_mv AT stefanmunneke n2acetamido2deoxybdglucopyranosyln3azidopropylomethylhydroxylamine
AT bridgetlstocker n2acetamido2deoxybdglucopyranosyln3azidopropylomethylhydroxylamine
AT mattiesmtimmer n2acetamido2deoxybdglucopyranosyln3azidopropylomethylhydroxylamine
AT graemejgainsford n2acetamido2deoxybdglucopyranosyln3azidopropylomethylhydroxylamine
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