N-(2-Acetamido-2-deoxy-β-d-glucopyranosyl)-N-(3-azidopropyl)-O-methylhydroxylamine

N-(2-Acetamido-2-deoxy-β-d-glucopyranosyl)-N-(3-azidopropyl)-O-methylhydroxylamine

The structure of the title compound, C12H23N5O6, solved using adequate data from a thin crystal plate, confirmed that this useful glycoconjugate was obtained in the ring-closed β-pyranose configuration with 4C1 conformation. The molecules are bound by O—H...O(OH) hydrogen bonds, notably in a zigzag...

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Bibliographic Details
Main Authors: Stefan Munneke, Bridget L. Stocker, Mattie S. M. Timmer, Graeme J. Gainsford
Format: Article
Language:English
Published: International Union of Crystallography 2016-03-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
oxyamine glycoside
carbohydrate
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989016002164
Description
Summary:The structure of the title compound, C12H23N5O6, solved using adequate data from a thin crystal plate, confirmed that this useful glycoconjugate was obtained in the ring-closed β-pyranose configuration with 4C1 conformation. The molecules are bound by O—H...O(OH) hydrogen bonds, notably in a zigzag C(2) chain along the short b (screw) axis, supplemented with an R22(12) O—H...O(carbonyl) link along the a axis and other C(2) links. The absolute configuration was not unambiguously determined but was known from the synthetic chemistry, which used natural 2-acetamido-2-deoxy-d-glucose as the starting material.
ISSN:2056-9890

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