Tetraethylammonium (acetylacetonato)bromidotricarbonylrhenate(I)

Tetraethylammonium (acetylacetonato)bromidotricarbonylrhenate(I)

In the title compound, (C8H20N)[ReBr(C5H7O2)(CO)3], the ReI atom in the rhenate anion is surrounded by three carbonyl ligands orientated in a facial arrangement, a bromide ligand and an acetylacetonate ligand, leading to a distorted octahedral ReC3BrO2 coordination with a O—Re&...

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Main Authors: Andreas Roodt, Hendrik G. Visser, Alice Brink
Format: Article
Language:English
Published: International Union of Crystallography 2011-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810050105
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spelling doaj-6ccd0f98613a4f098fe12beae22bffb02020-11-24T21:31:01ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-01-01671m34m3510.1107/S1600536810050105Tetraethylammonium (acetylacetonato)bromidotricarbonylrhenate(I)Andreas RoodtHendrik G. VisserAlice BrinkIn the title compound, (C8H20N)[ReBr(C5H7O2)(CO)3], the ReI atom in the rhenate anion is surrounded by three carbonyl ligands orientated in a facial arrangement, a bromide ligand and an acetylacetonate ligand, leading to a distorted octahedral ReC3BrO2 coordination with a O—Re—O bite angle of 85.66 (7)°. An array of C—H...O and C—H...Br hydrogen-bonding interactions between the cations and the surrounding rhenate anions stabilize the crystal structure. http://scripts.iucr.org/cgi-bin/paper?S1600536810050105
collection DOAJ
language English
format Article
sources DOAJ
author Andreas Roodt
Hendrik G. Visser
Alice Brink
spellingShingle Andreas Roodt
Hendrik G. Visser
Alice Brink
Tetraethylammonium (acetylacetonato)bromidotricarbonylrhenate(I)
Acta Crystallographica Section E
author_facet Andreas Roodt
Hendrik G. Visser
Alice Brink
author_sort Andreas Roodt
title Tetraethylammonium (acetylacetonato)bromidotricarbonylrhenate(I)
title_short Tetraethylammonium (acetylacetonato)bromidotricarbonylrhenate(I)
title_full Tetraethylammonium (acetylacetonato)bromidotricarbonylrhenate(I)
title_fullStr Tetraethylammonium (acetylacetonato)bromidotricarbonylrhenate(I)
title_full_unstemmed Tetraethylammonium (acetylacetonato)bromidotricarbonylrhenate(I)
title_sort tetraethylammonium (acetylacetonato)bromidotricarbonylrhenate(i)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-01-01
description In the title compound, (C8H20N)[ReBr(C5H7O2)(CO)3], the ReI atom in the rhenate anion is surrounded by three carbonyl ligands orientated in a facial arrangement, a bromide ligand and an acetylacetonate ligand, leading to a distorted octahedral ReC3BrO2 coordination with a O—Re—O bite angle of 85.66 (7)°. An array of C—H...O and C—H...Br hydrogen-bonding interactions between the cations and the surrounding rhenate anions stabilize the crystal structure.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810050105
work_keys_str_mv AT andreasroodt tetraethylammoniumacetylacetonatobromidotricarbonylrhenatei
AT hendrikgvisser tetraethylammoniumacetylacetonatobromidotricarbonylrhenatei
AT alicebrink tetraethylammoniumacetylacetonatobromidotricarbonylrhenatei
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