Experimental Study on the Isotopes Exchange in CO Molecular

It was studied that the rearrangement of oxygen isotopes and carbon isotopes in CO molecular caused by thermodynamic equilibrium in the presence of catalyst. The appropriate reaction conditions was obtained by analyzing the reactants of 12C18O and 13C16O as well as the reaction products 12C16O and 1...

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Main Authors: LONG Lei, XU Bao-yun, JIANG Yong-yue
Format: Article
Language:zho
Published: Editorial Board of Journal of Isotopes 2015-01-01
Series:Journal of Isotopes
Subjects:
Online Access:http://www.tws.org.cn/CN/10.7538/tws.2015.28.01.0037
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spelling doaj-6c9f7af63ce840509eb3c4528590fbde2020-11-25T01:10:13ZzhoEditorial Board of Journal of IsotopesJournal of Isotopes1000-75121000-75122015-01-01281374010.7538/tws.2015.28.01.0037 Experimental Study on the Isotopes Exchange in CO MolecularLONG Lei0XU Bao-yun1JIANG Yong-yue2LI Hu-linJI Yong-zheTIAN Ye-shengIt was studied that the rearrangement of oxygen isotopes and carbon isotopes in CO molecular caused by thermodynamic equilibrium in the presence of catalyst. The appropriate reaction conditions was obtained by analyzing the reactants of 12C18O and 13C16O as well as the reaction products 12C16O and 13C18O. The effects of temperature, pressure and space velocity on the conversion of 12C18O were studied in the experiments. It shows that the conversion of 12C18O can reach 80% at the conditions of 260 Torr, 400 ℃ and space velocity of 0.5 mL/(g•min). http://www.tws.org.cn/CN/10.7538/tws.2015.28.01.0037isotope chemical exchange reaction catalysis
collection DOAJ
language zho
format Article
sources DOAJ
author LONG Lei
XU Bao-yun
JIANG Yong-yue
spellingShingle LONG Lei
XU Bao-yun
JIANG Yong-yue
Experimental Study on the Isotopes Exchange in CO Molecular
Journal of Isotopes
isotope chemical exchange reaction catalysis
author_facet LONG Lei
XU Bao-yun
JIANG Yong-yue
author_sort LONG Lei
title Experimental Study on the Isotopes Exchange in CO Molecular
title_short Experimental Study on the Isotopes Exchange in CO Molecular
title_full Experimental Study on the Isotopes Exchange in CO Molecular
title_fullStr Experimental Study on the Isotopes Exchange in CO Molecular
title_full_unstemmed Experimental Study on the Isotopes Exchange in CO Molecular
title_sort experimental study on the isotopes exchange in co molecular
publisher Editorial Board of Journal of Isotopes
series Journal of Isotopes
issn 1000-7512
1000-7512
publishDate 2015-01-01
description It was studied that the rearrangement of oxygen isotopes and carbon isotopes in CO molecular caused by thermodynamic equilibrium in the presence of catalyst. The appropriate reaction conditions was obtained by analyzing the reactants of 12C18O and 13C16O as well as the reaction products 12C16O and 13C18O. The effects of temperature, pressure and space velocity on the conversion of 12C18O were studied in the experiments. It shows that the conversion of 12C18O can reach 80% at the conditions of 260 Torr, 400 ℃ and space velocity of 0.5 mL/(g•min).
topic isotope chemical exchange reaction catalysis
url http://www.tws.org.cn/CN/10.7538/tws.2015.28.01.0037
work_keys_str_mv AT longlei experimentalstudyontheisotopesexchangeincomolecular
AT xubaoyun experimentalstudyontheisotopesexchangeincomolecular
AT jiangyongyue experimentalstudyontheisotopesexchangeincomolecular
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