Recycling Y and Eu from Waste Fluorescent Powder and High Temperature Solid-State Synthesis of Y2O3:Eu Phosphors

Y2O3:Eu were prepared through precursors synthesized by leaching tests, removing impurities, enrichment of Y and Eu from residual purified liquors, annealing treatment, and high temperature solid-state reaction method, which is the most suitable for large-scale production. The analysis of product sh...

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Bibliographic Details
Main Authors: Xiaodong Chen, Nian Liu, Guangjun Mei, Mingming Yu
Format: Article
Language:English
Published: MDPI AG 2017-03-01
Series:Minerals
Subjects:
Online Access:http://www.mdpi.com/2075-163X/7/3/44
Description
Summary:Y2O3:Eu were prepared through precursors synthesized by leaching tests, removing impurities, enrichment of Y and Eu from residual purified liquors, annealing treatment, and high temperature solid-state reaction method, which is the most suitable for large-scale production. The analysis of product shows that the purity is 99.42%. The resultant powders were characterized by X-ray diffraction (XRD), differential thermal analysis (TG-DTA), scanning electron microscope (SEM), and photoluminescence (PL). Compared with the commercial phosphors, the XRD spectrum of the product samples revealed the synthesized particles to have a pure cubic Y2O3:Eu structure without any impurities in the crystalline phase. On the morphology, the Y2O3:Eu particles synthesized by a combustion and high temperature solid state process with sintering aids, were large and uniform. For luminescence property, the emission intensity of Y2O3:Eu phosphors synthesized by combustion process and high temperature solid state process with sintering aids were higher than those without sintering aids, at 1400 °C.
ISSN:2075-163X