Tetrakis(μ-4-azidobenzoato-κ2O:O′)bis[(N,N-dimethylformamide-κO)copper(II)]

Tetrakis(μ-4-azidobenzoato-κ2O:O′)bis[(N,N-dimethylformamide-κO)copper(II)]

The binuclear title compound, [Cu2(C7H4N3O2)4(C3H7NO)2], is a discrete metal–organic compound having a paddle-wheel-type structure. The Cu...Cu distance is 2.6366 (5) Å and an inversion center is located at the mid-point of this bond. The CuII c...

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Main Author: Aidong Wang
Format: Article
Language:English
Published: International Union of Crystallography 2012-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811050999
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spelling doaj-6c066660752640e79bdb0b42e645a20e2020-11-25T00:55:55ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-01-01681m43m4310.1107/S1600536811050999Tetrakis(μ-4-azidobenzoato-κ2O:O′)bis[(N,N-dimethylformamide-κO)copper(II)]Aidong WangThe binuclear title compound, [Cu2(C7H4N3O2)4(C3H7NO)2], is a discrete metal–organic compound having a paddle-wheel-type structure. The Cu...Cu distance is 2.6366 (5) Å and an inversion center is located at the mid-point of this bond. The CuII cation is coordinated by four carboxylate O atoms from four 4-azidobenzoate ligands, and one O atom from a dimethylformamide molecule, forming an overall distorted octahedral geometry when the Cu...Cu bond is also considered.http://scripts.iucr.org/cgi-bin/paper?S1600536811050999
collection DOAJ
language English
format Article
sources DOAJ
author Aidong Wang
spellingShingle Aidong Wang
Tetrakis(μ-4-azidobenzoato-κ2O:O′)bis[(N,N-dimethylformamide-κO)copper(II)]
Acta Crystallographica Section E
author_facet Aidong Wang
author_sort Aidong Wang
title Tetrakis(μ-4-azidobenzoato-κ2O:O′)bis[(N,N-dimethylformamide-κO)copper(II)]
title_short Tetrakis(μ-4-azidobenzoato-κ2O:O′)bis[(N,N-dimethylformamide-κO)copper(II)]
title_full Tetrakis(μ-4-azidobenzoato-κ2O:O′)bis[(N,N-dimethylformamide-κO)copper(II)]
title_fullStr Tetrakis(μ-4-azidobenzoato-κ2O:O′)bis[(N,N-dimethylformamide-κO)copper(II)]
title_full_unstemmed Tetrakis(μ-4-azidobenzoato-κ2O:O′)bis[(N,N-dimethylformamide-κO)copper(II)]
title_sort tetrakis(μ-4-azidobenzoato-κ2o:o′)bis[(n,n-dimethylformamide-κo)copper(ii)]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-01-01
description The binuclear title compound, [Cu2(C7H4N3O2)4(C3H7NO)2], is a discrete metal–organic compound having a paddle-wheel-type structure. The Cu...Cu distance is 2.6366 (5) Å and an inversion center is located at the mid-point of this bond. The CuII cation is coordinated by four carboxylate O atoms from four 4-azidobenzoate ligands, and one O atom from a dimethylformamide molecule, forming an overall distorted octahedral geometry when the Cu...Cu bond is also considered.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811050999
work_keys_str_mv AT aidongwang tetrakisamp9564azidobenzoatoamp9542ooamp8242bisnndimethylformamideamp954ocopperii
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