Tetrakis(μ-4-azidobenzoato-κ2O:O′)bis[(N,N-dimethylformamide-κO)copper(II)]

Tetrakis(μ-4-azidobenzoato-κ2O:O′)bis[(N,N-dimethylformamide-κO)copper(II)]

The binuclear title compound, [Cu2(C7H4N3O2)4(C3H7NO)2], is a discrete metal–organic compound having a paddle-wheel-type structure. The Cu...Cu distance is 2.6366 (5) Å and an inversion center is located at the mid-point of this bond. The CuII c...

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Bibliographic Details
Main Author: Aidong Wang
Format: Article
Language:English
Published: International Union of Crystallography 2012-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811050999
Description
Summary:The binuclear title compound, [Cu2(C7H4N3O2)4(C3H7NO)2], is a discrete metal–organic compound having a paddle-wheel-type structure. The Cu...Cu distance is 2.6366 (5) Å and an inversion center is located at the mid-point of this bond. The CuII cation is coordinated by four carboxylate O atoms from four 4-azidobenzoate ligands, and one O atom from a dimethylformamide molecule, forming an overall distorted octahedral geometry when the Cu...Cu bond is also considered.
ISSN:1600-5368

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