trans-Bis(ethylenediamine-κ2N,N′)bis(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2λ6,3-oxathiazin-3-ido-κN)copper(II)

trans-Bis(ethylenediamine-κ2N,N′)bis(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2λ6,3-oxathiazin-3-ido-κN)copper(II)

In the crystal structure of the title compound, [Cu(C4H4NO4S)2(C2H8N2)2], the Cu2+ ion resides on a centre of symmetry. The environment of Cu2+ ion is a distorted octahedron. The axial bond lengths between the CuII ion and the N atoms are considerably longer than the equatorial bond distances betwee...

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Main Authors: Necmi Dege, Güneş Demirtaş, Hasan Içbudak
Format: Article
Language:English
Published: International Union of Crystallography 2012-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811051658
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spelling doaj-6be9e01ee0104f1b9d8cf6b1ead43ab22020-11-25T00:51:26ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-01-01681m47m4810.1107/S1600536811051658trans-Bis(ethylenediamine-κ2N,N′)bis(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2λ6,3-oxathiazin-3-ido-κN)copper(II)Necmi DegeGüneş DemirtaşHasan IçbudakIn the crystal structure of the title compound, [Cu(C4H4NO4S)2(C2H8N2)2], the Cu2+ ion resides on a centre of symmetry. The environment of Cu2+ ion is a distorted octahedron. The axial bond lengths between the CuII ion and the N atoms are considerably longer than the equatorial bond distances between the CuII ion and the N atoms of the ethylenediamine ligand as a consequence of the Jahn–Teller effect. The molecular conformation is stabilized by intramolecular N—H...O hydrogen bonds. In the crystal, molecules are connected by intermolecular N—H...O hydrogen bonds into chains running along the a axis.http://scripts.iucr.org/cgi-bin/paper?S1600536811051658
collection DOAJ
language English
format Article
sources DOAJ
author Necmi Dege
Güneş Demirtaş
Hasan Içbudak
spellingShingle Necmi Dege
Güneş Demirtaş
Hasan Içbudak
trans-Bis(ethylenediamine-κ2N,N′)bis(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2λ6,3-oxathiazin-3-ido-κN)copper(II)
Acta Crystallographica Section E
author_facet Necmi Dege
Güneş Demirtaş
Hasan Içbudak
author_sort Necmi Dege
title trans-Bis(ethylenediamine-κ2N,N′)bis(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2λ6,3-oxathiazin-3-ido-κN)copper(II)
title_short trans-Bis(ethylenediamine-κ2N,N′)bis(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2λ6,3-oxathiazin-3-ido-κN)copper(II)
title_full trans-Bis(ethylenediamine-κ2N,N′)bis(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2λ6,3-oxathiazin-3-ido-κN)copper(II)
title_fullStr trans-Bis(ethylenediamine-κ2N,N′)bis(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2λ6,3-oxathiazin-3-ido-κN)copper(II)
title_full_unstemmed trans-Bis(ethylenediamine-κ2N,N′)bis(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2λ6,3-oxathiazin-3-ido-κN)copper(II)
title_sort trans-bis(ethylenediamine-κ2n,n′)bis(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2λ6,3-oxathiazin-3-ido-κn)copper(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-01-01
description In the crystal structure of the title compound, [Cu(C4H4NO4S)2(C2H8N2)2], the Cu2+ ion resides on a centre of symmetry. The environment of Cu2+ ion is a distorted octahedron. The axial bond lengths between the CuII ion and the N atoms are considerably longer than the equatorial bond distances between the CuII ion and the N atoms of the ethylenediamine ligand as a consequence of the Jahn–Teller effect. The molecular conformation is stabilized by intramolecular N—H...O hydrogen bonds. In the crystal, molecules are connected by intermolecular N—H...O hydrogen bonds into chains running along the a axis.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811051658
work_keys_str_mv AT necmidege transbisethylenediamineamp9542nnamp8242bis6methyl224trioxo34dihydro12amp95563oxathiazin3idoamp954ncopperii
AT gamp252neamp351demirtaamp351 transbisethylenediamineamp9542nnamp8242bis6methyl224trioxo34dihydro12amp95563oxathiazin3idoamp954ncopperii
AT hasaniamp231budak transbisethylenediamineamp9542nnamp8242bis6methyl224trioxo34dihydro12amp95563oxathiazin3idoamp954ncopperii
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