Metodologias eletroanalíticas para a determinação de herbicidas triazínicos por voltametria de onda quadrada e técnicas de deconvolução Electroanalytical methodologies for the determination of triazine herbiacides by square wave voltammetry and deconvolution techniques

<abstract language="eng">This work describes the development of electroanalytical methodologies for the determination of atrazine, ametrine and simazine by square wave voltammetry on a mercury electrode. For pure atrazine and pure ametrine, the detection limits (DL) were 3.7 and 4.3...

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Bibliographic Details
Main Authors: Gustavo S. Garbellini, Valber A. Pedrosa, Giancarlo R. Salazar-Banda, Luis A. Avaca
Format: Article
Language:English
Published: Sociedade Brasileira de Química 2007-01-01
Series:Química Nova
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422007000800039
Description
Summary:<abstract language="eng">This work describes the development of electroanalytical methodologies for the determination of atrazine, ametrine and simazine by square wave voltammetry on a mercury electrode. For pure atrazine and pure ametrine, the detection limits (DL) were 3.7 and 4.3 µg L-1, respectively, while they increased to 4.8 and 6.5 µg L-1 in the presence of 3.0 x 10-6 mol L-1 of the other component (a mathematical deconvolution program was used in the mixture cases). The voltammetric response for simazine could not be separated from that of atrazine and measurements were carried out only in pure simazine solutions (DL: 7.5 µg L-1).
ISSN:0100-4042
1678-7064