Aqua(benzamidato-κN)bis[3,5-difluoro-2-(pyridin-2-yl)phenyl-κC1]iridium(III) methanol monosolvate

Aqua(benzamidato-κN)bis[3,5-difluoro-2-(pyridin-2-yl)phenyl-κC1]iridium(III) methanol monosolvate

In the title compound, [Ir(C11H6F2N)2(C7H6NO)(H2O)]·CH3OH, the IrIII ion adopts an octahedral geometry, and is coordinated by two 3,5-difluoro-2-(pyridin-2-yl)phenyl ligands, one molecule of water and one benzamidate anion. The two 2-(4,6-difluorophenyl)pyridyl ligands are arranged in a...

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Main Authors: Feng Wu, Songlin Zhang, Yuqiang Ding
Format: Article
Language:English
Published: International Union of Crystallography 2012-03-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812005922
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spelling doaj-6b2cace1504546629c295a62aa02c9bd2020-11-25T01:50:50ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-03-01683m310m31010.1107/S1600536812005922Aqua(benzamidato-κN)bis[3,5-difluoro-2-(pyridin-2-yl)phenyl-κC1]iridium(III) methanol monosolvateFeng WuSonglin ZhangYuqiang DingIn the title compound, [Ir(C11H6F2N)2(C7H6NO)(H2O)]·CH3OH, the IrIII ion adopts an octahedral geometry, and is coordinated by two 3,5-difluoro-2-(pyridin-2-yl)phenyl ligands, one molecule of water and one benzamidate anion. The two 2-(4,6-difluorophenyl)pyridyl ligands are arranged in a cis-C,C′ and trans-N,N′ fashion. Additionally, there is a bystanding methanol molecule outside the coordination sphere of the IrIII ion. In the crystal, molecules of the title compound are linked by O—H...O and O—H...N hydrogen bonds. One F atom of each ligand is equally disordered over two sites. The C atom of the solvent molecule is likewise disordered over two sites in a 0.589 (11):0.411 (11) ratio.http://scripts.iucr.org/cgi-bin/paper?S1600536812005922
collection DOAJ
language English
format Article
sources DOAJ
author Feng Wu
Songlin Zhang
Yuqiang Ding
spellingShingle Feng Wu
Songlin Zhang
Yuqiang Ding
Aqua(benzamidato-κN)bis[3,5-difluoro-2-(pyridin-2-yl)phenyl-κC1]iridium(III) methanol monosolvate
Acta Crystallographica Section E
author_facet Feng Wu
Songlin Zhang
Yuqiang Ding
author_sort Feng Wu
title Aqua(benzamidato-κN)bis[3,5-difluoro-2-(pyridin-2-yl)phenyl-κC1]iridium(III) methanol monosolvate
title_short Aqua(benzamidato-κN)bis[3,5-difluoro-2-(pyridin-2-yl)phenyl-κC1]iridium(III) methanol monosolvate
title_full Aqua(benzamidato-κN)bis[3,5-difluoro-2-(pyridin-2-yl)phenyl-κC1]iridium(III) methanol monosolvate
title_fullStr Aqua(benzamidato-κN)bis[3,5-difluoro-2-(pyridin-2-yl)phenyl-κC1]iridium(III) methanol monosolvate
title_full_unstemmed Aqua(benzamidato-κN)bis[3,5-difluoro-2-(pyridin-2-yl)phenyl-κC1]iridium(III) methanol monosolvate
title_sort aqua(benzamidato-κn)bis[3,5-difluoro-2-(pyridin-2-yl)phenyl-κc1]iridium(iii) methanol monosolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-03-01
description In the title compound, [Ir(C11H6F2N)2(C7H6NO)(H2O)]·CH3OH, the IrIII ion adopts an octahedral geometry, and is coordinated by two 3,5-difluoro-2-(pyridin-2-yl)phenyl ligands, one molecule of water and one benzamidate anion. The two 2-(4,6-difluorophenyl)pyridyl ligands are arranged in a cis-C,C′ and trans-N,N′ fashion. Additionally, there is a bystanding methanol molecule outside the coordination sphere of the IrIII ion. In the crystal, molecules of the title compound are linked by O—H...O and O—H...N hydrogen bonds. One F atom of each ligand is equally disordered over two sites. The C atom of the solvent molecule is likewise disordered over two sites in a 0.589 (11):0.411 (11) ratio.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812005922
work_keys_str_mv AT fengwu aquabenzamidatoamp954nbis35difluoro2pyridin2ylphenylamp954c1iridiumiiimethanolmonosolvate
AT songlinzhang aquabenzamidatoamp954nbis35difluoro2pyridin2ylphenylamp954c1iridiumiiimethanolmonosolvate
AT yuqiangding aquabenzamidatoamp954nbis35difluoro2pyridin2ylphenylamp954c1iridiumiiimethanolmonosolvate
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