Piperazine/N-methylpiperazine/N,N’-dimethylpiperazine as an Aqueous Solvent for Carbon Dioxide Capture

• Main Authors: Freeman Stephanie A., Chen Xi, Nguyen Thu, Rafique Humera, Xu Qing, Rochelle Gary T.
• Format: Article
• Language: English
• Published: EDP Sciences 2014-09-01
• Series: Oil & Gas Science and Technology
• Online Access: http://dx.doi.org/10.2516/ogst/2012089

A blend of piperazine (PZ), N-methylpiperazine (MPZ) and N,N’-dimethylpiperazine (DMPZ) is described as a novel CO2 capture solvent for aqueous absorption-stripping. This blend provides improved solid solubility and heat of absorption compared to concentrated PZ. No insolubility was observed for regions of high CO2 loading, unlike PZ solvents. The blend performed like concentrated PZ in terms of CO2 capacity and CO2 absorption rate, both of which were more than double that of a traditional 7 molal (30 wt%) MonoEthanolAmine (MEA). Thermal equilibrium was established between the three constituent amines that increases the thermal stability compared to traditional blended solvents. The primary drawback of this novel solvent system is enhanced amine volatility at absorber conditions compared with both concentrated PZ and MEA.