Manganese and Cobalt Salts of Para-Amino-Benzoic Acid Supported on Silica Gel as Oxidizing Catalysts

Para-Aminobenzoic acid is supported on silica gel via reaction of activated silica gel and p-aminobenzoic acid which is then converted to its manganese and cobalt salts. A mixture of the manganese and cobalt salts of the acid is used to catalyze allylic and benzylic alcohols to their corresponding c...

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Bibliographic Details
Main Authors: Mohammad M. Hashemi, Dadkhoda Chazanfari
Format: Article
Language:English
Published: Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR 1994-12-01
Series:Iranian Journal of Chemistry & Chemical Engineering
Subjects:
Online Access:http://www.ijcce.ac.ir/article_10920_4115fbe44ac6d8e733ae4242085faa42.pdf
Description
Summary:Para-Aminobenzoic acid is supported on silica gel via reaction of activated silica gel and p-aminobenzoic acid which is then converted to its manganese and cobalt salts. A mixture of the manganese and cobalt salts of the acid is used to catalyze allylic and benzylic alcohols to their corresponding carbonyl compounds in reasonable yields using oxygen or air. Reactions are clean and the catalysts can be recovered easily and reused repeatedly.
ISSN:1021-9986
1021-9986