Kinetic and thermodynamic approaches on Rhodamine B adsorption onto pomegranate peel

In the present study, the adsorption potential of pomegranate peel for the removal of Rhodamine B (RhB) was investigated in a batch system. Kinetic and thermodynamic studies of adsorption were conducted. The rate adsorption of RhB was rapid, attained equilibrium at about 120 ​min, at which the adsor...

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Bibliographic Details
Main Authors: Rajae Ghibate, Omar Senhaji, Rachid Taouil
Format: Article
Language:English
Published: Elsevier 2021-06-01
Series:Case Studies in Chemical and Environmental Engineering
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2666016420300761
Description
Summary:In the present study, the adsorption potential of pomegranate peel for the removal of Rhodamine B (RhB) was investigated in a batch system. Kinetic and thermodynamic studies of adsorption were conducted. The rate adsorption of RhB was rapid, attained equilibrium at about 120 ​min, at which the adsorption capacity is close to 30,47 ​mg/g, and this in the initial dye concentration of 100 ​mg/L. The kinetic modeling of RhB adsorption was investigated using four celebrated models: pseudo-first order, pseudo-second order, Elovich, and intraparticle diffusion. According to the values of R2, RMSE, ARE, and χ2 it was found that the pseudo-second order model provided a better fit to kinetic data. The results also show that intraparticle diffusion is not the only rate-limiting step on RhB adsorption onto pomegranate peel. Moreover, the thermodynamic study revealed no-spontaneous and endothermic nature of the adsorption process.
ISSN:2666-0164