Poly[tetraaquadi-μ4-oxalato-lutetium(III)potassium]
In the title compound, [KLu(C2O4)2(H2O)4]n, the LuIII ion lies on a site of overline{4} symmetry in a dodecahedron defined by eight O atoms from four oxalate ligands. The K atom lies on another site of the same symmetry and is coordinated by four oxalate O atoms and four O water atoms. The mid-point...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811042061 |
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doaj-6aa8146158b04c90a225404fec65e3982020-11-24T21:52:46ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-11-016711m1591m159110.1107/S1600536811042061Poly[tetraaquadi-μ4-oxalato-lutetium(III)potassium]Feng-Ming ZhangTao-Zhu SunGuang-Feng HouPeng-Fei YanGuang-Ming LiIn the title compound, [KLu(C2O4)2(H2O)4]n, the LuIII ion lies on a site of overline{4} symmetry in a dodecahedron defined by eight O atoms from four oxalate ligands. The K atom lies on another site of the same symmetry and is coordinated by four oxalate O atoms and four O water atoms. The mid-point of the C—C bond of the oxalate group lies on an inversion center. In the packing structure, each oxalate ligand links two Lu(III) and two K atoms, forming a three-dimensional open framework with channels running along [001]. Intermolecular O—H...O hydrogen bonds occur.http://scripts.iucr.org/cgi-bin/paper?S1600536811042061 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Feng-Ming Zhang Tao-Zhu Sun Guang-Feng Hou Peng-Fei Yan Guang-Ming Li |
| spellingShingle |
Feng-Ming Zhang Tao-Zhu Sun Guang-Feng Hou Peng-Fei Yan Guang-Ming Li Poly[tetraaquadi-μ4-oxalato-lutetium(III)potassium] Acta Crystallographica Section E |
| author_facet |
Feng-Ming Zhang Tao-Zhu Sun Guang-Feng Hou Peng-Fei Yan Guang-Ming Li |
| author_sort |
Feng-Ming Zhang |
| title |
Poly[tetraaquadi-μ4-oxalato-lutetium(III)potassium] |
| title_short |
Poly[tetraaquadi-μ4-oxalato-lutetium(III)potassium] |
| title_full |
Poly[tetraaquadi-μ4-oxalato-lutetium(III)potassium] |
| title_fullStr |
Poly[tetraaquadi-μ4-oxalato-lutetium(III)potassium] |
| title_full_unstemmed |
Poly[tetraaquadi-μ4-oxalato-lutetium(III)potassium] |
| title_sort |
poly[tetraaquadi-μ4-oxalato-lutetium(iii)potassium] |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2011-11-01 |
| description |
In the title compound, [KLu(C2O4)2(H2O)4]n, the LuIII ion lies on a site of overline{4} symmetry in a dodecahedron defined by eight O atoms from four oxalate ligands. The K atom lies on another site of the same symmetry and is coordinated by four oxalate O atoms and four O water atoms. The mid-point of the C—C bond of the oxalate group lies on an inversion center. In the packing structure, each oxalate ligand links two Lu(III) and two K atoms, forming a three-dimensional open framework with channels running along [001]. Intermolecular O—H...O hydrogen bonds occur. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536811042061 |
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