Hybrid organic–inorganic perovskite ferroelectrics bring light to semiconducting applications: Bandgap engineering as a starting point
Ferroelectrics are attractive due to their great application potential in information storage, optoelectronics, spintronics and sensing. As an important characteristic affecting semiconducting applications, the energy band structure is important for the development of light-emitting devices. Althoug...
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Online Access: | http://dx.doi.org/10.1063/5.0039082 |
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doaj-6a8e09ecd3f347e7b894a48e2311b67f2021-05-04T14:07:59ZengAIP Publishing LLCAPL Materials2166-532X2021-04-0194040901040901-1210.1063/5.0039082Hybrid organic–inorganic perovskite ferroelectrics bring light to semiconducting applications: Bandgap engineering as a starting pointJie Yao0Qiang Pan1Zi-Jie Feng2Yu-An Xiong3Tai-Ting Sha4Hao-Ran Ji5Zhu-Xiao Gu6Yu-Meng You7Jiangsu Key Laboratory for Science and Applications of Molecular Ferroelectrics, Southeast University, Nanjing 211189, ChinaJiangsu Key Laboratory for Science and Applications of Molecular Ferroelectrics, Southeast University, Nanjing 211189, ChinaJiangsu Key Laboratory for Science and Applications of Molecular Ferroelectrics, Southeast University, Nanjing 211189, ChinaJiangsu Key Laboratory for Science and Applications of Molecular Ferroelectrics, Southeast University, Nanjing 211189, ChinaJiangsu Key Laboratory for Science and Applications of Molecular Ferroelectrics, Southeast University, Nanjing 211189, ChinaJiangsu Key Laboratory for Science and Applications of Molecular Ferroelectrics, Southeast University, Nanjing 211189, ChinaJiangsu Key Laboratory for Science and Applications of Molecular Ferroelectrics, Southeast University, Nanjing 211189, ChinaJiangsu Key Laboratory for Science and Applications of Molecular Ferroelectrics, Southeast University, Nanjing 211189, ChinaFerroelectrics are attractive due to their great application potential in information storage, optoelectronics, spintronics and sensing. As an important characteristic affecting semiconducting applications, the energy band structure is important for the development of light-emitting devices. Although it is a tremendous challenge to tune the bandgap in inorganic ferroelectric materials due to the strict requirement of structural symmetry for the fragile ferroelectricity, hybrid organic–inorganic perovskite (HOIP) ferroelectrics, which have a flexible structure, provide a new method to optimize the ferroelectric performance and bandgap. Based on the overview of methods for designing ferroelectrics, this Perspective systematically provides in-depth insight into the relationships between the structure–property and bandgap of HOIP ferroelectrics. In addition, we discussed the challenges and directions of HOIP ferroelectrics in semiconducting applications for the future.http://dx.doi.org/10.1063/5.0039082 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Jie Yao Qiang Pan Zi-Jie Feng Yu-An Xiong Tai-Ting Sha Hao-Ran Ji Zhu-Xiao Gu Yu-Meng You |
spellingShingle |
Jie Yao Qiang Pan Zi-Jie Feng Yu-An Xiong Tai-Ting Sha Hao-Ran Ji Zhu-Xiao Gu Yu-Meng You Hybrid organic–inorganic perovskite ferroelectrics bring light to semiconducting applications: Bandgap engineering as a starting point APL Materials |
author_facet |
Jie Yao Qiang Pan Zi-Jie Feng Yu-An Xiong Tai-Ting Sha Hao-Ran Ji Zhu-Xiao Gu Yu-Meng You |
author_sort |
Jie Yao |
title |
Hybrid organic–inorganic perovskite ferroelectrics bring light to semiconducting applications: Bandgap engineering as a starting point |
title_short |
Hybrid organic–inorganic perovskite ferroelectrics bring light to semiconducting applications: Bandgap engineering as a starting point |
title_full |
Hybrid organic–inorganic perovskite ferroelectrics bring light to semiconducting applications: Bandgap engineering as a starting point |
title_fullStr |
Hybrid organic–inorganic perovskite ferroelectrics bring light to semiconducting applications: Bandgap engineering as a starting point |
title_full_unstemmed |
Hybrid organic–inorganic perovskite ferroelectrics bring light to semiconducting applications: Bandgap engineering as a starting point |
title_sort |
hybrid organic–inorganic perovskite ferroelectrics bring light to semiconducting applications: bandgap engineering as a starting point |
publisher |
AIP Publishing LLC |
series |
APL Materials |
issn |
2166-532X |
publishDate |
2021-04-01 |
description |
Ferroelectrics are attractive due to their great application potential in information storage, optoelectronics, spintronics and sensing. As an important characteristic affecting semiconducting applications, the energy band structure is important for the development of light-emitting devices. Although it is a tremendous challenge to tune the bandgap in inorganic ferroelectric materials due to the strict requirement of structural symmetry for the fragile ferroelectricity, hybrid organic–inorganic perovskite (HOIP) ferroelectrics, which have a flexible structure, provide a new method to optimize the ferroelectric performance and bandgap. Based on the overview of methods for designing ferroelectrics, this Perspective systematically provides in-depth insight into the relationships between the structure–property and bandgap of HOIP ferroelectrics. In addition, we discussed the challenges and directions of HOIP ferroelectrics in semiconducting applications for the future. |
url |
http://dx.doi.org/10.1063/5.0039082 |
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