Hybrid organic–inorganic perovskite ferroelectrics bring light to semiconducting applications: Bandgap engineering as a starting point

Ferroelectrics are attractive due to their great application potential in information storage, optoelectronics, spintronics and sensing. As an important characteristic affecting semiconducting applications, the energy band structure is important for the development of light-emitting devices. Althoug...

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Main Authors: Jie Yao, Qiang Pan, Zi-Jie Feng, Yu-An Xiong, Tai-Ting Sha, Hao-Ran Ji, Zhu-Xiao Gu, Yu-Meng You
Format: Article
Language:English
Published: AIP Publishing LLC 2021-04-01
Series:APL Materials
Online Access:http://dx.doi.org/10.1063/5.0039082
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spelling doaj-6a8e09ecd3f347e7b894a48e2311b67f2021-05-04T14:07:59ZengAIP Publishing LLCAPL Materials2166-532X2021-04-0194040901040901-1210.1063/5.0039082Hybrid organic–inorganic perovskite ferroelectrics bring light to semiconducting applications: Bandgap engineering as a starting pointJie Yao0Qiang Pan1Zi-Jie Feng2Yu-An Xiong3Tai-Ting Sha4Hao-Ran Ji5Zhu-Xiao Gu6Yu-Meng You7Jiangsu Key Laboratory for Science and Applications of Molecular Ferroelectrics, Southeast University, Nanjing 211189, ChinaJiangsu Key Laboratory for Science and Applications of Molecular Ferroelectrics, Southeast University, Nanjing 211189, ChinaJiangsu Key Laboratory for Science and Applications of Molecular Ferroelectrics, Southeast University, Nanjing 211189, ChinaJiangsu Key Laboratory for Science and Applications of Molecular Ferroelectrics, Southeast University, Nanjing 211189, ChinaJiangsu Key Laboratory for Science and Applications of Molecular Ferroelectrics, Southeast University, Nanjing 211189, ChinaJiangsu Key Laboratory for Science and Applications of Molecular Ferroelectrics, Southeast University, Nanjing 211189, ChinaJiangsu Key Laboratory for Science and Applications of Molecular Ferroelectrics, Southeast University, Nanjing 211189, ChinaJiangsu Key Laboratory for Science and Applications of Molecular Ferroelectrics, Southeast University, Nanjing 211189, ChinaFerroelectrics are attractive due to their great application potential in information storage, optoelectronics, spintronics and sensing. As an important characteristic affecting semiconducting applications, the energy band structure is important for the development of light-emitting devices. Although it is a tremendous challenge to tune the bandgap in inorganic ferroelectric materials due to the strict requirement of structural symmetry for the fragile ferroelectricity, hybrid organic–inorganic perovskite (HOIP) ferroelectrics, which have a flexible structure, provide a new method to optimize the ferroelectric performance and bandgap. Based on the overview of methods for designing ferroelectrics, this Perspective systematically provides in-depth insight into the relationships between the structure–property and bandgap of HOIP ferroelectrics. In addition, we discussed the challenges and directions of HOIP ferroelectrics in semiconducting applications for the future.http://dx.doi.org/10.1063/5.0039082
collection DOAJ
language English
format Article
sources DOAJ
author Jie Yao
Qiang Pan
Zi-Jie Feng
Yu-An Xiong
Tai-Ting Sha
Hao-Ran Ji
Zhu-Xiao Gu
Yu-Meng You
spellingShingle Jie Yao
Qiang Pan
Zi-Jie Feng
Yu-An Xiong
Tai-Ting Sha
Hao-Ran Ji
Zhu-Xiao Gu
Yu-Meng You
Hybrid organic–inorganic perovskite ferroelectrics bring light to semiconducting applications: Bandgap engineering as a starting point
APL Materials
author_facet Jie Yao
Qiang Pan
Zi-Jie Feng
Yu-An Xiong
Tai-Ting Sha
Hao-Ran Ji
Zhu-Xiao Gu
Yu-Meng You
author_sort Jie Yao
title Hybrid organic–inorganic perovskite ferroelectrics bring light to semiconducting applications: Bandgap engineering as a starting point
title_short Hybrid organic–inorganic perovskite ferroelectrics bring light to semiconducting applications: Bandgap engineering as a starting point
title_full Hybrid organic–inorganic perovskite ferroelectrics bring light to semiconducting applications: Bandgap engineering as a starting point
title_fullStr Hybrid organic–inorganic perovskite ferroelectrics bring light to semiconducting applications: Bandgap engineering as a starting point
title_full_unstemmed Hybrid organic–inorganic perovskite ferroelectrics bring light to semiconducting applications: Bandgap engineering as a starting point
title_sort hybrid organic–inorganic perovskite ferroelectrics bring light to semiconducting applications: bandgap engineering as a starting point
publisher AIP Publishing LLC
series APL Materials
issn 2166-532X
publishDate 2021-04-01
description Ferroelectrics are attractive due to their great application potential in information storage, optoelectronics, spintronics and sensing. As an important characteristic affecting semiconducting applications, the energy band structure is important for the development of light-emitting devices. Although it is a tremendous challenge to tune the bandgap in inorganic ferroelectric materials due to the strict requirement of structural symmetry for the fragile ferroelectricity, hybrid organic–inorganic perovskite (HOIP) ferroelectrics, which have a flexible structure, provide a new method to optimize the ferroelectric performance and bandgap. Based on the overview of methods for designing ferroelectrics, this Perspective systematically provides in-depth insight into the relationships between the structure–property and bandgap of HOIP ferroelectrics. In addition, we discussed the challenges and directions of HOIP ferroelectrics in semiconducting applications for the future.
url http://dx.doi.org/10.1063/5.0039082
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