Crystal structure of chlorido{1-(2,3-dimethyl-5-oxido-1-phenyl-1H-pyrazol-2-ium-4-yl-κO)-2-[3-methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-ylidene-κO]hydrazin-1-ido-κN1}copper(II) from laboratory X-ray powder data

Crystal structure of chlorido{1-(2,3-dimethyl-5-oxido-1-phenyl-1H-pyrazol-2-ium-4-yl-κO)-2-[3-methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-ylidene-κO]hydrazin-1-ido-κN1}copper(II) from laboratory X-ray powder data

In the title compound, [Cu(C21H19N6O2)Cl], the CuII atom is in a slightly distorted square-planar coordination involving two O atoms from the pyrazolone rings [Cu—O = 2.088 (10) and 1.975 (10) Å], an N atom of the azo group [Cu—N = 2.048 (13) Å] and a chloride anion [Cu—Cl = 2.183 (5) Å]. The organi...

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Main Authors: Olga Kovalchukova, Van Nguen, Svetlana Strashnova, Dmitry Kuznetsov, Teimuraz Berikashvili
Format: Article
Language:English
Published: International Union of Crystallography 2015-02-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
azopyrazolone
copper complex
powder diffraction
Online Access:http://scripts.iucr.org/cgi-bin/paper?S205698901402756X
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spelling doaj-6a744f0c6eeb497f88e96a3c4b9ded442020-11-25T00:48:56ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902015-02-0171212412710.1107/S205698901402756Xvn2088Crystal structure of chlorido{1-(2,3-dimethyl-5-oxido-1-phenyl-1H-pyrazol-2-ium-4-yl-κO)-2-[3-methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-ylidene-κO]hydrazin-1-ido-κN1}copper(II) from laboratory X-ray powder dataOlga Kovalchukova0Van Nguen1Svetlana Strashnova2Dmitry Kuznetsov3Teimuraz Berikashvili4Peoples' Friendship University of Russia, 6 Miklukho-Mallaya, 117198 Moscow, RussiaPeoples' Friendship University of Russia, 6 Miklukho-Mallaya, 117198 Moscow, RussiaPeoples' Friendship University of Russia, 6 Miklukho-Mallaya, 117198 Moscow, RussiaMoscow State University of Design and Technology, 33 Sadovnicheskaya, 117997 Moscow, RussiaGeorgian Technical University, 77 Kostava, 0175 Tbilisi, GeorgiaIn the title compound, [Cu(C21H19N6O2)Cl], the CuII atom is in a slightly distorted square-planar coordination involving two O atoms from the pyrazolone rings [Cu—O = 2.088 (10) and 1.975 (10) Å], an N atom of the azo group [Cu—N = 2.048 (13) Å] and a chloride anion [Cu—Cl = 2.183 (5) Å]. The organic anions act as tridentate chelating ligands. The molecules stack in columns along the c axis.http://scripts.iucr.org/cgi-bin/paper?S205698901402756Xcrystal structureazopyrazolonecopper complexpowder diffraction
collection DOAJ
language English
format Article
sources DOAJ
author Olga Kovalchukova
Van Nguen
Svetlana Strashnova
Dmitry Kuznetsov
Teimuraz Berikashvili
spellingShingle Olga Kovalchukova
Van Nguen
Svetlana Strashnova
Dmitry Kuznetsov
Teimuraz Berikashvili
Crystal structure of chlorido{1-(2,3-dimethyl-5-oxido-1-phenyl-1H-pyrazol-2-ium-4-yl-κO)-2-[3-methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-ylidene-κO]hydrazin-1-ido-κN1}copper(II) from laboratory X-ray powder data
Acta Crystallographica Section E: Crystallographic Communications
crystal structure
azopyrazolone
copper complex
powder diffraction
author_facet Olga Kovalchukova
Van Nguen
Svetlana Strashnova
Dmitry Kuznetsov
Teimuraz Berikashvili
author_sort Olga Kovalchukova
title Crystal structure of chlorido{1-(2,3-dimethyl-5-oxido-1-phenyl-1H-pyrazol-2-ium-4-yl-κO)-2-[3-methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-ylidene-κO]hydrazin-1-ido-κN1}copper(II) from laboratory X-ray powder data
title_short Crystal structure of chlorido{1-(2,3-dimethyl-5-oxido-1-phenyl-1H-pyrazol-2-ium-4-yl-κO)-2-[3-methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-ylidene-κO]hydrazin-1-ido-κN1}copper(II) from laboratory X-ray powder data
title_full Crystal structure of chlorido{1-(2,3-dimethyl-5-oxido-1-phenyl-1H-pyrazol-2-ium-4-yl-κO)-2-[3-methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-ylidene-κO]hydrazin-1-ido-κN1}copper(II) from laboratory X-ray powder data
title_fullStr Crystal structure of chlorido{1-(2,3-dimethyl-5-oxido-1-phenyl-1H-pyrazol-2-ium-4-yl-κO)-2-[3-methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-ylidene-κO]hydrazin-1-ido-κN1}copper(II) from laboratory X-ray powder data
title_full_unstemmed Crystal structure of chlorido{1-(2,3-dimethyl-5-oxido-1-phenyl-1H-pyrazol-2-ium-4-yl-κO)-2-[3-methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-ylidene-κO]hydrazin-1-ido-κN1}copper(II) from laboratory X-ray powder data
title_sort crystal structure of chlorido{1-(2,3-dimethyl-5-oxido-1-phenyl-1h-pyrazol-2-ium-4-yl-κo)-2-[3-methyl-5-oxo-1-phenyl-4,5-dihydro-1h-pyrazol-4-ylidene-κo]hydrazin-1-ido-κn1}copper(ii) from laboratory x-ray powder data
publisher International Union of Crystallography
series Acta Crystallographica Section E: Crystallographic Communications
issn 2056-9890
publishDate 2015-02-01
description In the title compound, [Cu(C21H19N6O2)Cl], the CuII atom is in a slightly distorted square-planar coordination involving two O atoms from the pyrazolone rings [Cu—O = 2.088 (10) and 1.975 (10) Å], an N atom of the azo group [Cu—N = 2.048 (13) Å] and a chloride anion [Cu—Cl = 2.183 (5) Å]. The organic anions act as tridentate chelating ligands. The molecules stack in columns along the c axis.
topic crystal structure
azopyrazolone
copper complex
powder diffraction
url http://scripts.iucr.org/cgi-bin/paper?S205698901402756X
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AT vannguen crystalstructureofchlorido123dimethyl5oxido1phenyl1hpyrazol2ium4ylko23methyl5oxo1phenyl45dihydro1hpyrazol4ylidenekohydrazin1idokn1copperiifromlaboratoryxraypowderdata
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